Catalytic Conversion of Ethanol Into 1,3-Butadiene: Achievements and Prospects: A Review

The results of the studies of the processes of catalytic conversion of ethanol to 1,3-butadiene during the last decade are summarized. Modern ideas about the mechanisms of such processes are discussed. The influence of the composition and method of preparation, as well as the nature of modifying add...

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Bibliographic Details
Published in:Theoretical and experimental chemistry 2020-09, Vol.56 (4), p.213-242
Main Authors: Kyriienko, P. I., Larina, O. V., Soloviev, S. O., Orlyk, S. M.
Format: Article
Language:English
Subjects:
Additives
Alcohol
Alcohol, Denatured
Butadiene
Catalytic converters
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Conversion
Ethanol
Selectivity
Sustainable development
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Summary:The results of the studies of the processes of catalytic conversion of ethanol to 1,3-butadiene during the last decade are summarized. Modern ideas about the mechanisms of such processes are discussed. The influence of the composition and method of preparation, as well as the nature of modifying additives on redox and acid–base characteristics of the catalyst surface, which determine their activity and selectivity, is reviewed. Particular attention is paid to the conversion of ethanol–aqueous mixtures. The directions of further research for the implementation of the process of obtaining 1,3-butadiene from ethanol and ethanol–aqueous mixtures are outlined.
ISSN:0040-5760
1573-935X
DOI:10.1007/s11237-020-09654-2