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Reaction-induced phase transitions with block copolymers in solution and bulk
Reaction-induced phase transitions (RIPTs) encompass a broad range of synthetic strategies that use chemical reactions to drive the organization of macromolecules into complex, nanoscale morphologies. A diverse set of chemical reactions are now available which can alter a polymer's composition...
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Published in: | Polymer chemistry 2021-01, Vol.12 (1), p.12-28 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Reaction-induced phase transitions (RIPTs) encompass a broad range of synthetic strategies that use chemical reactions to drive the organization of macromolecules into complex, nanoscale morphologies. A diverse set of chemical reactions are now available which can alter a polymer's composition and can provide access to a rich landscape of tailorable morphologies in both solution and bulk. In this review, we highlight advances in RIPTs that rely upon functionalization, deprotection, conjugation, chain-scission, grafting, and polymerization to induce
disorder-to-order
or
order-to-order
phase transitions
in situ
. To date, polymerization-induced self-assembly is the most well-established RIPT, but only represents one of a broader family of reactions for inducing macromolecular organization. This contribution explores the wider field of chemical reactions for inducing macromolecular self-assembly or reorganization and takes a comprehensive look at significant and recent developments in this flourishing area of research.
Reaction-induced phase transitions use chemical reactions to drive macromolecular organisation and self-assembly. This review highlights significant and recent advancements in this burgeoning field. |
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ISSN: | 1759-9954 1759-9962 |
DOI: | 10.1039/d0py00722f |