Boosting the sodium storage of the 1T/2H MoS2@SnO2 heterostructure via a fast surface redox reaction

The sluggish kinetics and large volume expansion arising from the large ionic radius of Na+ remain elusive weaknesses of sodium ion batteries (SIBs). Here, we report a transition from bulk diffusion to surface-dominant pseudocapacitive charge storage by nanoscaling and heterostructuring, which enabl...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2021-01, Vol.9 (1), p.463-471
Main Authors: Gui, Dayong, Wei, Zhijie, Chen, Jian, Yan, Liwei, Li, Jun, Zhang, Peixin, Zhao, Chenyang
Format: Article
Language:English
Subjects:
Basal plane
Batteries
Charge transfer
Electrochemistry
Heterostructures
Kinetics
Molybdenum disulfide
Nanoparticles
Redox reactions
Self-assembly
Sodium
Sodium-ion batteries
Specific capacity
Storage
Surface charge
Synergistic effect
Tin dioxide
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Summary:The sluggish kinetics and large volume expansion arising from the large ionic radius of Na+ remain elusive weaknesses of sodium ion batteries (SIBs). Here, we report a transition from bulk diffusion to surface-dominant pseudocapacitive charge storage by nanoscaling and heterostructuring, which enables fast and stable charge storage kinetics for SIBs. An electronic attraction induced self-assembly strategy was developed for the synthesis of the 1T/2H MoS2@SnO2 heterostructure. Ultrasmall SnO2 nanoparticles with a low crystallinity were uniformly distributed on the basal plane of MoS2. The intercalated SnO2 serves as an interfacial pillar to restrict the restacking of MoS2 nanosheets, whereas dual-phase 1T/2H MoS2 provides a continuous network for efficient charge transfer and restrains the aggregation of NaxSn. As a result, the 1T/2H MoS2@SnO2 heterostructure exhibits a higher specific capacity (626 mA h g−1 at 0.1 A g−1), and superior cycling and rate capabilities (262 mA h g−1 at 2 A g−1 for 500 cycles) compared to the raw MoS2 and 2H MoS2@SnO2 counterparts. Electrochemical kinetics analyses reveal that the charge transfer kinetics are boosted by the synergistic effect between the 1T/2H MoS2 and SnO2 nanoparticles. Quantitative examination into the origin demonstrated that the Na+ storage is dominated by the fast surface redox reaction, which endows the heterostructure with a durable high rate capability.
ISSN:2050-7488
2050-7496
DOI:10.1039/d0ta08711d