Silicon solar cells with nitrogen-rich SiNx/Si interfacial passivation by low-energy nitrogen-ion implantation

• Published in: Solar energy materials and solar cells 2021-01, Vol.220, p.110858, Article 110858
• Main Authors: Sahu, Rajkumar, Palei, Srikanta, Choi, Jaeho, Ji, Hyung Yong, Kim, Keunjoo
• Format: Article
• Language: English
• Subjects: Annealing; Defects; Efficiency; Electric contacts; Emitters; Energy; Fluence; Insulation layer; Interface; Ion implantation; Ions; Low temperature; Nitrogen; Nitrogen ions; Nitrogenation; Passivity; Photovoltaic cells; Quantum efficiency; Silicon; Silicon solar cell; Solar cells
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2020.110858

We investigated low energy nitrogen ion implantation into the SiNx/Si interfacial layer of silicon solar cells using various energies and fluences, followed by a thermal annealing process. The low energy implanted nitrogen ions penetrated into the SiNx antireflection layer and reached the Si emitter layer. However, ions could not pass through the Ag electrode contact layer and were unable to form the contact passivation layer. A low energy nitrogen ion implanted cell showed the formation of a rich nitrogen layer in the SiNx/Si interfacial area and an increase in electrical performance. With increasing nitrogen ion implantation energy, cells were damaged and suffered decreasing efficiency compared to a reference cell. Increasing the fluence of nitrogen ions also caused a decrease in cell efficiency. After a low temperature annealing process, the cell efficiency recovered almost to the pre-implantation point of the reference cells and showed a similar recovery in their photoreflectance and quantum efficiency. The low-energy nitrogen ion implantation showed the improved cell efficiency of 17.28% for the energy of 12 keV with a fluence of 1 × 1013 cm-2. •We fabricated Si solar cell by nitrogen ion implantation with low energy.•We examined changes in the energy level according to the fixed ion fluence and vice versa.•Decreasing energy will increase cell quality at fixed nitrogen ion fluencies.•The results indicate that the nitrogen-rich interface by implantation is related to cell efficiency improvement..