First Stereoselective Total Synthesis of Modiolin

The first stereoselective total synthesis of the linear pentaketide Modiolin has been performed via Jacobsen’ hydrolytic kinetic resolution and 2C-Wittig homologation as key steps.

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Bibliographic Details
Published in:Russian journal of organic chemistry 2020-12, Vol.56 (11), p.2028-2031
Main Authors: Rao, G. Padma, Mohan, B. Sathish, Siddaiah, V.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Homology
Organic Chemistry
Stereoselectivity
Synthesis
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Description
Summary:The first stereoselective total synthesis of the linear pentaketide Modiolin has been performed via Jacobsen’ hydrolytic kinetic resolution and 2C-Wittig homologation as key steps.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428020110184