Synthesis of Cross-linked Carboxyl Modified Polyvinyl Alcohol and its Application in Selective Adsorption Separation of Cu(II) from Cd(II) and Ni(II)

• Published in: Journal of polymers and the environment 2021, Vol.29 (1), p.28-37
• Main Authors: Zeng, Lelin, Zhou, Feixiang, Hu, Rong, Xie, Wanyun, Wang, Guoxiang, Yang, Caixia, Liang, Enxiang, Xu, Wenyuan, Van der Bruggen, Bart
• Format: Article
• Language: English
• Subjects: Acetic acid; Acrylic acid; Adsorption; Aqueous solutions; Azobisisobutyronitrile; Cadmium; Carbon monoxide; Chemistry; Chemistry and Materials Science; Copolymers; Copper; Crosslinking; Environmental Chemistry; Environmental Engineering/Biotechnology; Ethanol; Exothermic reactions; Heavy metals; Hydrogels; Industrial Chemistry/Chemical Engineering; Industrial wastes; Industrial wastewater; Kinetics; Materials Science; Metal ions; Methylene bisacrylamide; Nickel; Original Paper; Polymer Sciences; Polyvinyl alcohol; Rate constants; Selective adsorption; Selectivity; Separation; Vinyl acetate; Wastewater
• ISSN: 1566-2543; 1572-8919
• DOI: 10.1007/s10924-020-01847-z

A cross-linked copolymer (XL-P(AA-co-VAc)) of vinyl acetate and acrylic acid was prepared using azobisisobutyronitrile as initiator and N , N’ -methylenebisacrylamide as crosslinker. Then, XL-P(AA-co-VAc) was reacted with ethanol to prepare a crosslinked carboxyl modified polyvinyl alcohol (XL-P(AA-co-VA)). The as-prepared XL-P(AA-CO-VA) hydrogel was characterized by FTIR, XRD, SEM and BET, and investigated as an selective heavy metal ion adsorbent. The adsorption characteristics of the XL-P(AA-CO-VA) hydrogel were studied with a aqueous solution containing ternary metal ions Cu(II), Cd(II) and Ni(II). It was found that XL-P(AA-CO-VA) can selectively adsorb Cu(II) in competition with Cd(II) and Ni(II), and the selectivity coefficients of 48 ( β Cu(II)/Cd(II) ) and 80 ( β Cu(II)/Ni(II) ) were obtained. The kinetics were demonstrated to match well with the pseudo-second order kinetics model with the rate constants ( K 2 , g/(mg•min)) of 3.71✕10 − 4 , 0.0011 and 0.0015 for Cu(II), Cd(II) and Ni(II), respectively. The equilibrium adsorption of Cu(II) to the XL-P(AA-CO-VA) hydrogel follows the Langmuir adsorption model with q max of 41.27 mg/g and K L of 0.94 L/mg. The thermodynamic studies indicate that Δ G 0 was negative and increased with temperature, and the adsorption process of XL-P(AA-CO-VA) for Cu(II) ion was spontaneous and exothermic. Δ H and Δ S were − 56.57 kJ/mol and − 171.18 J·(mol·K) −1 , respectively. The XL-P(AA-CO-VA) hydrogel is of interest for the selective separation of Cu(II) from industrial wastewater containing Cd(II) and Ni(II).