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An EXAFS study of phenanthroline-holmium complex
A holmium complex, [ Ho ( phen ) 2 ( H 2 O) 2 ( Cl ) 2 ]Cl.H 2 O, as a luminescent/bio probe has been made and characterized using extended X-ray absorption fine structure (EXAFS) as well as IR spectroscopy, UV-Vis spectroscopy, and elemental analysis. Structural data of the formed Ho(III)–phen spec...
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| Published in: | The European physical journal. D, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2021, Vol.75 (1), Article 38 |
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| Language: | English |
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| container_title | The European physical journal. D, Atomic, molecular, and optical physics |
| container_volume | 75 |
| creator | Shahedi, Abdolhamed Rahighi, Javad Bolorizadeh, Mohammad Agha |
| description | A holmium complex,
[
Ho
(
phen
)
2
(
H
2
O)
2
(
Cl
)
2
]Cl.H
2
O, as a luminescent/bio probe has been made and characterized using extended X-ray absorption fine structure (EXAFS) as well as IR spectroscopy, UV-Vis spectroscopy, and elemental analysis. Structural data of the formed Ho(III)–phen species are determined from the Ho
L
III
-edge EXAFS spectra as well as its
k
2
-weighted and
k
3
-weighted spectra. The coordination numbers and distances between the holmium and the first shell atoms, i.e., O, N, and Cl, are measured. The EXAFS spectra are also analyzed by Fourier transform of the normalized absorption coefficient into the molecular distance coordinates to further verify the determined Ho(III) structural model.
Graphic abstract |
| doi_str_mv | 10.1140/epjd/s10053-020-00019-x |
| format | article |
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[
Ho
(
phen
)
2
(
H
2
O)
2
(
Cl
)
2
]Cl.H
2
O, as a luminescent/bio probe has been made and characterized using extended X-ray absorption fine structure (EXAFS) as well as IR spectroscopy, UV-Vis spectroscopy, and elemental analysis. Structural data of the formed Ho(III)–phen species are determined from the Ho
L
III
-edge EXAFS spectra as well as its
k
2
-weighted and
k
3
-weighted spectra. The coordination numbers and distances between the holmium and the first shell atoms, i.e., O, N, and Cl, are measured. The EXAFS spectra are also analyzed by Fourier transform of the normalized absorption coefficient into the molecular distance coordinates to further verify the determined Ho(III) structural model.
Graphic abstract</description><identifier>ISSN: 1434-6060</identifier><identifier>EISSN: 1434-6079</identifier><identifier>DOI: 10.1140/epjd/s10053-020-00019-x</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Absorptivity ; Applications of Nonlinear Dynamics and Chaos Theory ; Atomic ; Coordination numbers ; Fine structure ; Fourier transforms ; Holmium ; Infrared spectroscopy ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Physics ; Physics and Astronomy ; Quantum Information Technology ; Quantum Physics ; Regular Article - Molecular Physics and Chemical Physics ; Spectra ; Spectroscopy/Spectrometry ; Spectrum analysis ; Spintronics ; Structural models ; X ray absorption</subject><ispartof>The European physical journal. D, Atomic, molecular, and optical physics, 2021, Vol.75 (1), Article 38</ispartof><rights>EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c280t-18c6b8a16743ae106b49c4a627d6a1af18288f0f04dee5afb629565734fbc7de3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Shahedi, Abdolhamed</creatorcontrib><creatorcontrib>Rahighi, Javad</creatorcontrib><creatorcontrib>Bolorizadeh, Mohammad Agha</creatorcontrib><title>An EXAFS study of phenanthroline-holmium complex</title><title>The European physical journal. D, Atomic, molecular, and optical physics</title><addtitle>Eur. Phys. J. D</addtitle><description>A holmium complex,
[
Ho
(
phen
)
2
(
H
2
O)
2
(
Cl
)
2
]Cl.H
2
O, as a luminescent/bio probe has been made and characterized using extended X-ray absorption fine structure (EXAFS) as well as IR spectroscopy, UV-Vis spectroscopy, and elemental analysis. Structural data of the formed Ho(III)–phen species are determined from the Ho
L
III
-edge EXAFS spectra as well as its
k
2
-weighted and
k
3
-weighted spectra. The coordination numbers and distances between the holmium and the first shell atoms, i.e., O, N, and Cl, are measured. The EXAFS spectra are also analyzed by Fourier transform of the normalized absorption coefficient into the molecular distance coordinates to further verify the determined Ho(III) structural model.
Graphic abstract</description><subject>Absorptivity</subject><subject>Applications of Nonlinear Dynamics and Chaos Theory</subject><subject>Atomic</subject><subject>Coordination numbers</subject><subject>Fine structure</subject><subject>Fourier transforms</subject><subject>Holmium</subject><subject>Infrared spectroscopy</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Quantum Information Technology</subject><subject>Quantum Physics</subject><subject>Regular Article - Molecular Physics and Chemical Physics</subject><subject>Spectra</subject><subject>Spectroscopy/Spectrometry</subject><subject>Spectrum analysis</subject><subject>Spintronics</subject><subject>Structural models</subject><subject>X ray absorption</subject><issn>1434-6060</issn><issn>1434-6079</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkM9LwzAYhoMoOKd_gwXPcV9-NEmPY2wqDDyo4C2kbeI22qYmLXT_vZ0VPXr63sP7vB88CN0SuCeEw8K2h3IRCUDKMFDAAEAyPJyhGeGMYwEyO__NAi7RVYyHsURTLmYIlk2yfl9uXpLY9eUx8S5pd7YxTbcLvto3Fu98Ve_7Oil83VZ2uEYXzlTR3vzcOXrbrF9Xj3j7_PC0Wm5xQRV0mKhC5MoQITkzloDIeVZwI6gshSHGEUWVcuCAl9amxuWCZqlIJeMuL2Rp2RzdTbtt8J-9jZ0--D4040tNuWKCZZkkY0tOrSL4GIN1ug372oSjJqBPevRJj5706FGP_tajh5FUExlHovmw4W__P_QLuARrRQ</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Shahedi, Abdolhamed</creator><creator>Rahighi, Javad</creator><creator>Bolorizadeh, Mohammad Agha</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>An EXAFS study of phenanthroline-holmium complex</title><author>Shahedi, Abdolhamed ; Rahighi, Javad ; Bolorizadeh, Mohammad Agha</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c280t-18c6b8a16743ae106b49c4a627d6a1af18288f0f04dee5afb629565734fbc7de3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Absorptivity</topic><topic>Applications of Nonlinear Dynamics and Chaos Theory</topic><topic>Atomic</topic><topic>Coordination numbers</topic><topic>Fine structure</topic><topic>Fourier transforms</topic><topic>Holmium</topic><topic>Infrared spectroscopy</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Quantum Information Technology</topic><topic>Quantum Physics</topic><topic>Regular Article - Molecular Physics and Chemical Physics</topic><topic>Spectra</topic><topic>Spectroscopy/Spectrometry</topic><topic>Spectrum analysis</topic><topic>Spintronics</topic><topic>Structural models</topic><topic>X ray absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shahedi, Abdolhamed</creatorcontrib><creatorcontrib>Rahighi, Javad</creatorcontrib><creatorcontrib>Bolorizadeh, Mohammad Agha</creatorcontrib><collection>CrossRef</collection><jtitle>The European physical journal. D, Atomic, molecular, and optical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shahedi, Abdolhamed</au><au>Rahighi, Javad</au><au>Bolorizadeh, Mohammad Agha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An EXAFS study of phenanthroline-holmium complex</atitle><jtitle>The European physical journal. D, Atomic, molecular, and optical physics</jtitle><stitle>Eur. Phys. J. D</stitle><date>2021</date><risdate>2021</risdate><volume>75</volume><issue>1</issue><artnum>38</artnum><issn>1434-6060</issn><eissn>1434-6079</eissn><abstract>A holmium complex,
[
Ho
(
phen
)
2
(
H
2
O)
2
(
Cl
)
2
]Cl.H
2
O, as a luminescent/bio probe has been made and characterized using extended X-ray absorption fine structure (EXAFS) as well as IR spectroscopy, UV-Vis spectroscopy, and elemental analysis. Structural data of the formed Ho(III)–phen species are determined from the Ho
L
III
-edge EXAFS spectra as well as its
k
2
-weighted and
k
3
-weighted spectra. The coordination numbers and distances between the holmium and the first shell atoms, i.e., O, N, and Cl, are measured. The EXAFS spectra are also analyzed by Fourier transform of the normalized absorption coefficient into the molecular distance coordinates to further verify the determined Ho(III) structural model.
Graphic abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1140/epjd/s10053-020-00019-x</doi></addata></record> |
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| identifier | ISSN: 1434-6060 |
| ispartof | The European physical journal. D, Atomic, molecular, and optical physics, 2021, Vol.75 (1), Article 38 |
| issn | 1434-6060 1434-6079 |
| language | eng |
| recordid | cdi_proquest_journals_2483639971 |
| source | Springer Link |
| subjects | Absorptivity Applications of Nonlinear Dynamics and Chaos Theory Atomic Coordination numbers Fine structure Fourier transforms Holmium Infrared spectroscopy Molecular Optical and Plasma Physics Physical Chemistry Physics Physics and Astronomy Quantum Information Technology Quantum Physics Regular Article - Molecular Physics and Chemical Physics Spectra Spectroscopy/Spectrometry Spectrum analysis Spintronics Structural models X ray absorption |
| title | An EXAFS study of phenanthroline-holmium complex |
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