[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure

The complex [Re(CO) 3 (bipy)(ClO 4 )] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO) 3 (H 2 O,EtOH) 3 ](ClO 4 ) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffr...

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Bibliographic Details
Published in:Russian journal of general chemistry 2020-12, Vol.90 (12), p.2333-2337
Main Authors: Miroslavov, A. E., Sidorenko, G. V., Tyupina, M. Yu, Gurzhiy, V. V.
Format: Article
Language:English
Subjects:
Carbon monoxide
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Coordination
Crystal structure
Crystallization
Crystals
Dichloromethane
Ethanol
Infrared spectroscopy
Molecular structure
Single crystals
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Summary:The complex [Re(CO) 3 (bipy)(ClO 4 )] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO) 3 (H 2 O,EtOH) 3 ](ClO 4 ) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac -position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363220120178