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Polypyrrole-based nanocomposites architecture as multifunctional material for futuristic energy storage applications

Nanoscale designing of polymer based architectures is essential to enhance the efficiency of energy storage devices for their potential applications in modern day technology. Usually, two phase nanocomposites develop a single type of interface between matrix and filler, causing an increase in dielec...

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Published in:Journal of alloys and compounds 2021-02, Vol.855, p.157341, Article 157341
Main Authors: Ansar, Muhammad Tamoor, Ali, Asad, Mustafa, Ghulam M., Afzal, Fatima, Ishaq, Saira, Kanwal, Farah, Naseem, Shahzad, Atiq, Shahid
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cited_by cdi_FETCH-LOGICAL-c337t-fc4be1ba327a0896bc91977d6c9c5d98a4dd86b440b6873c959409617228ce153
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container_start_page 157341
container_title Journal of alloys and compounds
container_volume 855
creator Ansar, Muhammad Tamoor
Ali, Asad
Mustafa, Ghulam M.
Afzal, Fatima
Ishaq, Saira
Kanwal, Farah
Naseem, Shahzad
Atiq, Shahid
description Nanoscale designing of polymer based architectures is essential to enhance the efficiency of energy storage devices for their potential applications in modern day technology. Usually, two phase nanocomposites develop a single type of interface between matrix and filler, causing an increase in dielectric constant and high energy density at the cast of charge discharge efficiency. Herein, we report a three phase (GO/CoFe2O4/PPy) novel class of nanocomposites capable of exhibiting high energy density storage. Three different components of this nanocomposite were synthesized using Hummer’s method, sol-gel auto-combustion technique and polymerization route, separately which were then combined using solution mixing technique in the presence of 0.3 M solution of FeCl3·6H2O. The development of inverse spinel structure of CoFe2O4 and its phase stability was analyzed using X-ray diffraction. Evolution of a variety of nanoarchitectures was confirmed by a field emission scanning electron microscope and its consequences on dielectric and ferroelectric response were probed via precision impedance analyzer and precision multiferroic tester. For the identification of functional groups, Fourier transform infrared spectroscopy was employed and conductive nature was examined using their I–V response curves. Dielectric response of PPy mediated by GO and CFO contents was explained on the basis of Maxwell-Wagner model. The magnetic hysteresis loops were employed and maximum magnetization, remnant magnetization, coercivity and squareness ratio were measured. Using polarization-electric field loops, energy density measurements were carried out which revealed the potential of these nanocomposites for energy storage devices. [Display omitted] •Facile and impurity free synthesis of GO/CoFe2O4/PPy (1%, 5%, 10%, 15%, 20%) nanocomposites.•Maxwell-Wagner interfacial polarization agreed with Koop’s multilayer capacitors formation.•Emergence of one semi-circle revealed the dominant grain boundaries effect in Nyquist plot.•A significant increase in saturation and remanent magnetization upon increase of GO and CFO contents.•Confirmation of wide range utilization of nanocomposites in energy storage applications.
doi_str_mv 10.1016/j.jallcom.2020.157341
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For the identification of functional groups, Fourier transform infrared spectroscopy was employed and conductive nature was examined using their I–V response curves. Dielectric response of PPy mediated by GO and CFO contents was explained on the basis of Maxwell-Wagner model. The magnetic hysteresis loops were employed and maximum magnetization, remnant magnetization, coercivity and squareness ratio were measured. Using polarization-electric field loops, energy density measurements were carried out which revealed the potential of these nanocomposites for energy storage devices. 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subjects Charge efficiency
Cobalt ferrites
Coercivity
Complex electric modulus
Dielectric analysis
Electric fields
Energy
Energy storage
Ferric chloride
Ferroelectricity
Field emission microscopy
Flux density
Fourier transforms
Functional groups
Hysteresis loops
Iron chlorides
Magnetization
Multifunctional materials
Nanocomposites
Phase stability
Polymer-ceramic nanocomposites
Polypyrroles
Recoverable energy density
Sol-gel processes
Stability analysis
title Polypyrrole-based nanocomposites architecture as multifunctional material for futuristic energy storage applications
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