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Methanesulfonic anhydride-promoted sustainable synthesis of thioesters from feedstock acids and thiols
An unprecedented metal-, halogen- and solvent-free, MSAA-promoted S -carbonylation of thiols with feedstock acids has been developed. This new transformation provides an efficient and atom-economic strategy for the synthesis of thioesters in a single operation from readily available and inexpensive...
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| Published in: | Journal of chemical sciences (Bangalore, India) India), 2021-02, Vol.133 (1), Article 20 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c385t-7d794b61aee8ebd48b40c0339c8b5fdfc9e770d9f90b2666811e01f36435abc83 |
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| container_issue | 1 |
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| container_title | Journal of chemical sciences (Bangalore, India) |
| container_volume | 133 |
| creator | Singh, Pallavi Peddinti, Rama Krishna |
| description | An unprecedented metal-, halogen- and solvent-free, MSAA-promoted
S
-carbonylation of thiols with feedstock acids has been developed. This new transformation provides an efficient and atom-economic strategy for the synthesis of thioesters in a single operation from readily available and inexpensive starting materials. The reaction avoids the use of expensive and hazardous coupling reagents, bases and generates water as the only by-product, thus making this chemical synthetic process more viable, environment-friendly and contributing towards sustainable chemistry.
Graphic abstract
An efficient and novel strategy was established for dehydrative nucleophilic substitution reaction of feedstock acids with thiols, which systematically unravels the feasibility and practicality of thioester formation in a step- and atom-economical fashion. |
| doi_str_mv | 10.1007/s12039-020-01871-5 |
| format | article |
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S
-carbonylation of thiols with feedstock acids has been developed. This new transformation provides an efficient and atom-economic strategy for the synthesis of thioesters in a single operation from readily available and inexpensive starting materials. The reaction avoids the use of expensive and hazardous coupling reagents, bases and generates water as the only by-product, thus making this chemical synthetic process more viable, environment-friendly and contributing towards sustainable chemistry.
Graphic abstract
An efficient and novel strategy was established for dehydrative nucleophilic substitution reaction of feedstock acids with thiols, which systematically unravels the feasibility and practicality of thioester formation in a step- and atom-economical fashion.</description><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/s12039-020-01871-5</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Carbonyls ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Raw materials ; Reagents ; Regular Article ; Synthesis ; Thioesters ; Thiols</subject><ispartof>Journal of chemical sciences (Bangalore, India), 2021-02, Vol.133 (1), Article 20</ispartof><rights>Indian Academy of Sciences 2021</rights><rights>Indian Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-7d794b61aee8ebd48b40c0339c8b5fdfc9e770d9f90b2666811e01f36435abc83</citedby><cites>FETCH-LOGICAL-c385t-7d794b61aee8ebd48b40c0339c8b5fdfc9e770d9f90b2666811e01f36435abc83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Singh, Pallavi</creatorcontrib><creatorcontrib>Peddinti, Rama Krishna</creatorcontrib><title>Methanesulfonic anhydride-promoted sustainable synthesis of thioesters from feedstock acids and thiols</title><title>Journal of chemical sciences (Bangalore, India)</title><addtitle>J Chem Sci</addtitle><description>An unprecedented metal-, halogen- and solvent-free, MSAA-promoted
S
-carbonylation of thiols with feedstock acids has been developed. This new transformation provides an efficient and atom-economic strategy for the synthesis of thioesters in a single operation from readily available and inexpensive starting materials. The reaction avoids the use of expensive and hazardous coupling reagents, bases and generates water as the only by-product, thus making this chemical synthetic process more viable, environment-friendly and contributing towards sustainable chemistry.
Graphic abstract
An efficient and novel strategy was established for dehydrative nucleophilic substitution reaction of feedstock acids with thiols, which systematically unravels the feasibility and practicality of thioester formation in a step- and atom-economical fashion.</description><subject>Carbonyls</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Raw materials</subject><subject>Reagents</subject><subject>Regular Article</subject><subject>Synthesis</subject><subject>Thioesters</subject><subject>Thiols</subject><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kD1PwzAQhiMEEuXjDzBFYjac48R2RlTxJRWxwGw59pmkpEnxJUP_PaZFYmO6G573vdOTZVccbjiAuiVegKgZFMCAa8VZdZQtoFaCKQ7ieL-XTMhCnmZnRGsAoUslFll4wam1A9Lch3HoXG6Hdudj55Ft47gZJ_Q5zTTZbrBNjznthqlF6igfQz613Yg0YaQ8JDgPiJ6m0X3m1nWeUpffMz1dZCfB9oSXv_M8e3-4f1s-sdXr4_PybsWc0NXElFd12UhuETU2vtRNCQ6EqJ1uquCDq1Ep8HWooSmklJpzBB6ELEVlG6fFeXZ96E3Pf83pN7Me5zikk6YotZZ1UQiZqOJAuTgSRQxmG7uNjTvDwfz4NAefJvk0e5-mSiFxCFGChw-Mf9X_pL4BHlB61w</recordid><startdate>20210211</startdate><enddate>20210211</enddate><creator>Singh, Pallavi</creator><creator>Peddinti, Rama Krishna</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210211</creationdate><title>Methanesulfonic anhydride-promoted sustainable synthesis of thioesters from feedstock acids and thiols</title><author>Singh, Pallavi ; Peddinti, Rama Krishna</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-7d794b61aee8ebd48b40c0339c8b5fdfc9e770d9f90b2666811e01f36435abc83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Carbonyls</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Raw materials</topic><topic>Reagents</topic><topic>Regular Article</topic><topic>Synthesis</topic><topic>Thioesters</topic><topic>Thiols</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Pallavi</creatorcontrib><creatorcontrib>Peddinti, Rama Krishna</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Pallavi</au><au>Peddinti, Rama Krishna</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Methanesulfonic anhydride-promoted sustainable synthesis of thioesters from feedstock acids and thiols</atitle><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle><stitle>J Chem Sci</stitle><date>2021-02-11</date><risdate>2021</risdate><volume>133</volume><issue>1</issue><artnum>20</artnum><issn>0974-3626</issn><eissn>0973-7103</eissn><abstract>An unprecedented metal-, halogen- and solvent-free, MSAA-promoted
S
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Graphic abstract
An efficient and novel strategy was established for dehydrative nucleophilic substitution reaction of feedstock acids with thiols, which systematically unravels the feasibility and practicality of thioester formation in a step- and atom-economical fashion.</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12039-020-01871-5</doi></addata></record> |
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| ispartof | Journal of chemical sciences (Bangalore, India), 2021-02, Vol.133 (1), Article 20 |
| issn | 0974-3626 0973-7103 |
| language | eng |
| recordid | cdi_proquest_journals_2488692236 |
| source | Springer Link; Free Full-Text Journals in Chemistry |
| subjects | Carbonyls Chemistry Chemistry and Materials Science Chemistry/Food Science Raw materials Reagents Regular Article Synthesis Thioesters Thiols |
| title | Methanesulfonic anhydride-promoted sustainable synthesis of thioesters from feedstock acids and thiols |
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