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Studies on uranium extraction from leach liquor of the mineralized shear zone at El-Missikat area using tri-n-octylamine
Fast extraction of uranium from Egyptian low-grade uranium mineralization sulfate leach liquor was studied with kerosene solutions of tri-n-octylamine (TOA). The parameters affecting uranium extraction were studied and the optimum conditions were determined. The equilibrium isotherm demonstrated the...
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Published in: | Journal of radioanalytical and nuclear chemistry 2021-02, Vol.327 (2), p.731-743 |
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creator | Ahmed, Mohammed Ramadan Mohammed, Hesham Samir El-Feky, Mohamed Galal Abdel-Monem, Yasser Kamal |
description | Fast extraction of uranium from Egyptian low-grade uranium mineralization sulfate leach liquor was studied with kerosene solutions of tri-n-octylamine (TOA). The parameters affecting uranium extraction were studied and the optimum conditions were determined. The equilibrium isotherm demonstrated the association of four moles of TOA per mole of uranium. Thermodynamic studies at different temperatures indicated that the extraction process was exothermic, favorable and spontaneous in nature. The organic phase loaded with uranyl sulfate under the optimum extraction conditions were examined by infrared spectrometry. The McCabe–Thiele plot for circuit of uranium with TOA predicted three extraction stages and two stripping stages. |
doi_str_mv | 10.1007/s10967-020-07545-3 |
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The parameters affecting uranium extraction were studied and the optimum conditions were determined. The equilibrium isotherm demonstrated the association of four moles of TOA per mole of uranium. Thermodynamic studies at different temperatures indicated that the extraction process was exothermic, favorable and spontaneous in nature. The organic phase loaded with uranyl sulfate under the optimum extraction conditions were examined by infrared spectrometry. 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subjects | Chemistry Chemistry and Materials Science Circuits Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Kerosene Liquors Mineralization Nuclear Chemistry Nuclear energy Nuclear Physics Physical Chemistry Radioactive substances Shear zone Sulfates Uranium |
title | Studies on uranium extraction from leach liquor of the mineralized shear zone at El-Missikat area using tri-n-octylamine |
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