Effect of Temperature, Time, and Cooling Rate on the Mineralogy, Morphology, and Reducibility of Iron Ore Sinter Analogues

• Published in: JOM (1989) 2021-01, Vol.73 (1), p.345-355
• Main Authors: Harvey, Tobin, Pownceby, Mark I., Chen, Jeff, Webster, Nathan A. S., Nguyen, Thi Bang Tuyen, Matthews, Leanne, O’Dea, Damien, Honeyands, Tom
• Format: Article
• Language: English
• Subjects: Aluminum; Calcium aluminum ferrite; Chemistry/Food Science; Cooling; Cooling rate; Earth Sciences; Electron probe microanalysis; Engineering; Environment; Gas mixtures; Gases; Gravimetric analysis; Iron compounds; Iron ores; Light; Microscopy; Mineralogy; Morphology; Optical microscopy; Physics; Porosity; Sinter; Sintering; Sintering of Oxides and Concentrates; Tablets; Temperature; Temperature effects; Tube furnaces; X-ray diffraction
• ISSN: 1047-4838; 1543-1851
• DOI: 10.1007/s11837-020-04452-6

Analogue sinter tablets were produced at temperatures between 1250°C and 1320°C, with a range of hold times and cooling rates. Platy silico-ferrite of calcium and aluminum (SFCA) morphology was identified in samples produced at 1250°C using reflected light microscopy; however, quantitative x-ray diffraction (XRD) identified the presence of the SFCA phase, with no SFCA-I detected. This proves that the platy SFCA morphology common in analysis by reflected light microscopy cannot be attributed to the SFCA-I mineral without further analysis. Micro-XRD and electron probe micro-analysis (EPMA) were carried out on an area of platy SFCA confirming this result. The sinter analogue tablets were reduced in a 30% CO, 70% N 2 gas mixture at 900°C in a tube furnace thermo-gravimetric analyzer. The degree of reduction of the tablets in this study was found to be controlled by the porosity of the samples, rather than by the morphology or mineralogy of the bonding phase.