Characterization of an amorphous materials hybrid polymer electrolyte based on a LiNO3-doped, CMC-PVA blend for application in an electrical double layer capacitor

• Published in: Materials chemistry and physics 2020-10, Vol.253, p.123312, Article 123312
• Main Authors: Zulkifli, A., Saadiah, M.A., Mazuki, N.F., Samsudin, A.S.
• Format: Article
• Language: English
• Subjects: Amorphous materials; Capacitors; CMC-PVA hybrid; Diffusion coefficient; Electrical impedance; Electrical resistivity; Electrochemical devices; Electrolytes; Fourier transforms; Ion currents; Ionic mobility; Ions; Li; Polymer electrolytes; Polymers; Room temperature; Spectrum analysis; Voltammetry
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2020.123312

In the present work, hybrid polymer electrolytes consisting of a CMC-PVA blend doped with various amounts of LiNO3 was produced using the casting technique. The structural and ionic conductivity of the prepared samples were studied by using Fourier transform infrared (FTIR) spectroscopy, x-ray diffraction (XRD), scanning electron microscopy (SEM) and electrical impedance spectroscopy (EIS) analyses. The optimum ionic conductivity at room temperature was achieved at 3.54 × 10−3 S cm−1 with the addition of 20 wt % of LiNO3 which showed the lowest percentage of crystallinity. IR-deconvolution revealed that the ionic conductivity is dependent on the ionic mobility and diffusion coefficient. Linear sweep voltammetry was performed where the highest ionic conducting sample is electrochemically stable up to 1.43 V. The highest conducting sample was fabricated into an electrical double layer capacitor (EDLC) and was characterized by using cyclic voltammetry and galvanostatic charge-discharge (GCD) for their electrochemical stability performance. The GCD profile showed that the fabricated EDLC is stable to operate up to the 5000th cycles with the average specific capacitance of ~100 F/g. [Display omitted] •Hybrid polymer electrolytes were prepared based CMC-PVA doped LiNO3.•Li+ which originate from LiNO3 has improved the crystalline phase of CMC-PVA.•The room temperature ionic conductivity achieved the maximum value at ~10−3 S cm−1.•The fabricated EDLC exhibited favorable performance in electrochemical characteristics.