Mechanism of Synthesis and Structure Formation of Hybrid Oligomers Based on Complex Oligophenylene Compounds with Metals

The reaction mechanism of the formation of hybrid oligomers based on complexes compounds of metal and oligophenylene is considered. The structure of compounds formed in such a reaction is determined. The effect of the addition of dimethyl sulfoxide on the increase in the yield of the main reaction p...

Full description

Saved in:
Bibliographic Details
Published in:Journal of superhard materials 2020-11, Vol.42 (6), p.443-445
Main Authors: Savchenko, D. O., Pashchenko, E. O., Kaidash, O. M., Kukharenko, S. A., Buriachek, O. V., Rumiantseva, Yu. Yu, Skorokhod, S. V., Romanenko, Y. M.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination compounds
Dimethyl sulfoxide
Letters to the Editor
Oligomers
Physical Chemistry
Reaction mechanisms
Reaction products
Synthesis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The reaction mechanism of the formation of hybrid oligomers based on complexes compounds of metal and oligophenylene is considered. The structure of compounds formed in such a reaction is determined. The effect of the addition of dimethyl sulfoxide on the increase in the yield of the main reaction product was found, and a mechanism of this effect was proposed, based on the change in the conformational features of oligophenylene in the synthesis process. The produced oligomers are promising as binders for composites of superhard materials.
ISSN:1063-4576
1934-9408
DOI:10.3103/S106345762006009X