Synthesis and characterization of boron‐acrylate/Santa Barbara Amorphous‐15 polymer composite

In the present work, boron‐acrylate/Santa Barbara Amorphous (SBA)‐15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA‐15 was functionalized with 3‐(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA‐15 surfa...

Full description

Saved in:
Bibliographic Details
Published in:Journal of applied polymer science 2021-05, Vol.138 (20), p.n/a
Main Authors: Aliyeva, Nargiz, Canak, Tuba Cakir, Serhatlı, İbrahim Ersin
Format: Article
Language:English
Subjects:
Boron
boron acrylate
Chemical bonds
Chemical synthesis
Free radical polymerization
Free radicals
Hydrofluoric acid
Infrared analysis
Materials science
mesoporous silica
mesoporous silica/polymer composite
NMR
Nuclear magnetic resonance
Polymer matrix composites
Polymers
SBA‐15
Silicon dioxide
Structural analysis
Thermogravimetric analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3
cites cdi_FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3
container_end_page n/a
container_issue 20
container_start_page
container_title Journal of applied polymer science
container_volume 138
creator Aliyeva, Nargiz
Canak, Tuba Cakir
Serhatlı, İbrahim Ersin
description In the present work, boron‐acrylate/Santa Barbara Amorphous (SBA)‐15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA‐15 was functionalized with 3‐(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA‐15 surface. The structural analysis was evaluated via Fourier‐transform infrared spectroscopy and solid‐state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X‐ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron‐acrylate/SBA‐15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.
doi_str_mv 10.1002/app.50445
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2492230927</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2492230927</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3</originalsourceid><addsrcrecordid>eNp10L9OwzAQBnALgUQpDLyBJSaGtGcnTuKxVPyTKlGpMFtnx1FTJXGwU6Ew8Qg8I09CoKxMN9zvu5M-Qi4ZzBgAn2PXzQQkiTgiEwYyi5KU58dkMu5YlEspTslZCDsAxgSkE4Kboe23NlSBYltQs0WPpre-ese-ci11JdXOu_br4xONH2rs7XyDbY_0Br0eMV00zndbtw8jYYJ2rh4a66lxTedC1dtzclJiHezF35ySl7vb5-VDtHq6f1wuVpGJ40RExrJMa2CQMbQg4iKWghdG5JkUBYNEaBApcFtmFgqZoiwTiaW0GnSelrGOp-TqcLfz7nVvQ692bu_b8aXiieQ8BsmzUV0flPEuBG9L1fmqQT8oBuqnQTU2qH4bHO38YN-q2g7_Q7VYrw-Jb57fdQc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2492230927</pqid></control><display><type>article</type><title>Synthesis and characterization of boron‐acrylate/Santa Barbara Amorphous‐15 polymer composite</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Aliyeva, Nargiz ; Canak, Tuba Cakir ; Serhatlı, İbrahim Ersin</creator><creatorcontrib>Aliyeva, Nargiz ; Canak, Tuba Cakir ; Serhatlı, İbrahim Ersin</creatorcontrib><description>In the present work, boron‐acrylate/Santa Barbara Amorphous (SBA)‐15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA‐15 was functionalized with 3‐(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA‐15 surface. The structural analysis was evaluated via Fourier‐transform infrared spectroscopy and solid‐state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X‐ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron‐acrylate/SBA‐15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.50445</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley &amp; Sons, Inc</publisher><subject>Boron ; boron acrylate ; Chemical bonds ; Chemical synthesis ; Free radical polymerization ; Free radicals ; Hydrofluoric acid ; Infrared analysis ; Materials science ; mesoporous silica ; mesoporous silica/polymer composite ; NMR ; Nuclear magnetic resonance ; Polymer matrix composites ; Polymers ; SBA‐15 ; Silicon dioxide ; Structural analysis ; Thermogravimetric analysis</subject><ispartof>Journal of applied polymer science, 2021-05, Vol.138 (20), p.n/a</ispartof><rights>2021 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3</citedby><cites>FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3</cites><orcidid>0000-0001-7455-2092 ; 0000-0002-7893-2479 ; 0000-0001-8048-3978</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Aliyeva, Nargiz</creatorcontrib><creatorcontrib>Canak, Tuba Cakir</creatorcontrib><creatorcontrib>Serhatlı, İbrahim Ersin</creatorcontrib><title>Synthesis and characterization of boron‐acrylate/Santa Barbara Amorphous‐15 polymer composite</title><title>Journal of applied polymer science</title><description>In the present work, boron‐acrylate/Santa Barbara Amorphous (SBA)‐15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA‐15 was functionalized with 3‐(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA‐15 surface. The structural analysis was evaluated via Fourier‐transform infrared spectroscopy and solid‐state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X‐ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron‐acrylate/SBA‐15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.</description><subject>Boron</subject><subject>boron acrylate</subject><subject>Chemical bonds</subject><subject>Chemical synthesis</subject><subject>Free radical polymerization</subject><subject>Free radicals</subject><subject>Hydrofluoric acid</subject><subject>Infrared analysis</subject><subject>Materials science</subject><subject>mesoporous silica</subject><subject>mesoporous silica/polymer composite</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>SBA‐15</subject><subject>Silicon dioxide</subject><subject>Structural analysis</subject><subject>Thermogravimetric analysis</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp10L9OwzAQBnALgUQpDLyBJSaGtGcnTuKxVPyTKlGpMFtnx1FTJXGwU6Ew8Qg8I09CoKxMN9zvu5M-Qi4ZzBgAn2PXzQQkiTgiEwYyi5KU58dkMu5YlEspTslZCDsAxgSkE4Kboe23NlSBYltQs0WPpre-ese-ci11JdXOu_br4xONH2rs7XyDbY_0Br0eMV00zndbtw8jYYJ2rh4a66lxTedC1dtzclJiHezF35ySl7vb5-VDtHq6f1wuVpGJ40RExrJMa2CQMbQg4iKWghdG5JkUBYNEaBApcFtmFgqZoiwTiaW0GnSelrGOp-TqcLfz7nVvQ692bu_b8aXiieQ8BsmzUV0flPEuBG9L1fmqQT8oBuqnQTU2qH4bHO38YN-q2g7_Q7VYrw-Jb57fdQc</recordid><startdate>20210520</startdate><enddate>20210520</enddate><creator>Aliyeva, Nargiz</creator><creator>Canak, Tuba Cakir</creator><creator>Serhatlı, İbrahim Ersin</creator><general>John Wiley &amp; Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-7455-2092</orcidid><orcidid>https://orcid.org/0000-0002-7893-2479</orcidid><orcidid>https://orcid.org/0000-0001-8048-3978</orcidid></search><sort><creationdate>20210520</creationdate><title>Synthesis and characterization of boron‐acrylate/Santa Barbara Amorphous‐15 polymer composite</title><author>Aliyeva, Nargiz ; Canak, Tuba Cakir ; Serhatlı, İbrahim Ersin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Boron</topic><topic>boron acrylate</topic><topic>Chemical bonds</topic><topic>Chemical synthesis</topic><topic>Free radical polymerization</topic><topic>Free radicals</topic><topic>Hydrofluoric acid</topic><topic>Infrared analysis</topic><topic>Materials science</topic><topic>mesoporous silica</topic><topic>mesoporous silica/polymer composite</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>SBA‐15</topic><topic>Silicon dioxide</topic><topic>Structural analysis</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aliyeva, Nargiz</creatorcontrib><creatorcontrib>Canak, Tuba Cakir</creatorcontrib><creatorcontrib>Serhatlı, İbrahim Ersin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aliyeva, Nargiz</au><au>Canak, Tuba Cakir</au><au>Serhatlı, İbrahim Ersin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of boron‐acrylate/Santa Barbara Amorphous‐15 polymer composite</atitle><jtitle>Journal of applied polymer science</jtitle><date>2021-05-20</date><risdate>2021</risdate><volume>138</volume><issue>20</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>In the present work, boron‐acrylate/Santa Barbara Amorphous (SBA)‐15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA‐15 was functionalized with 3‐(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA‐15 surface. The structural analysis was evaluated via Fourier‐transform infrared spectroscopy and solid‐state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X‐ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron‐acrylate/SBA‐15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.</abstract><cop>Hoboken, USA</cop><pub>John Wiley &amp; Sons, Inc</pub><doi>10.1002/app.50445</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-7455-2092</orcidid><orcidid>https://orcid.org/0000-0002-7893-2479</orcidid><orcidid>https://orcid.org/0000-0001-8048-3978</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0021-8995
ispartof Journal of applied polymer science, 2021-05, Vol.138 (20), p.n/a
issn 0021-8995
1097-4628
language eng
recordid cdi_proquest_journals_2492230927
source Wiley-Blackwell Read & Publish Collection
subjects Boron
boron acrylate
Chemical bonds
Chemical synthesis
Free radical polymerization
Free radicals
Hydrofluoric acid
Infrared analysis
Materials science
mesoporous silica
mesoporous silica/polymer composite
NMR
Nuclear magnetic resonance
Polymer matrix composites
Polymers
SBA‐15
Silicon dioxide
Structural analysis
Thermogravimetric analysis
title Synthesis and characterization of boron‐acrylate/Santa Barbara Amorphous‐15 polymer composite
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T13%3A49%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20characterization%20of%20boron%E2%80%90acrylate/Santa%20Barbara%20Amorphous%E2%80%9015%20polymer%20composite&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Aliyeva,%20Nargiz&rft.date=2021-05-20&rft.volume=138&rft.issue=20&rft.epage=n/a&rft.issn=0021-8995&rft.eissn=1097-4628&rft_id=info:doi/10.1002/app.50445&rft_dat=%3Cproquest_cross%3E2492230927%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3345-ce17bb01071ae053d3952dc58795d1045b05602ef7e0d96a9f49af9eb0b86f3b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2492230927&rft_id=info:pmid/&rfr_iscdi=true