One-pot cascade synthesis of α-diketones from aldehydes and ketones in water by using a bifunctional iron nanocomposite catalyst

A new methodology for the synthesis of α-diketones was reported via a one-pot cascade process from aldehydes and ketones catalyzed by a bifunctional iron nanocomposite using H 2 O 2 as a green oxidant in water. The one-pot strategy showed excellent catalytic stability, comprehensive suitability of s...

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2021-03, Vol.23 (5), p.1955-1959
Main Authors: Song, Tao, Zhou, Xin, Wang, Xiaoxue, Xiao, Jianliang, Yang, Yong
Format: Article
Language:English
Subjects:
Aldehydes
Biological activity
Catalysts
Diketones
Green chemistry
Hydrogen peroxide
Iron
Ketones
Nanocomposites
Oxidants
Oxidizing agents
Substrates
Synthesis
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Summary:A new methodology for the synthesis of α-diketones was reported via a one-pot cascade process from aldehydes and ketones catalyzed by a bifunctional iron nanocomposite using H 2 O 2 as a green oxidant in water. The one-pot strategy showed excellent catalytic stability, comprehensive suitability of substrates and important practical utility for directly synthesizing biologically active and medicinally valuable N-heterocycles via an intermittent process. A methodology for the synthesis of α-diketones was developed via a one-pot cascade process from aldehydes and ketones catalyzed by a bifunctional iron nanocomposite using H 2 O 2 as an oxidant in water.
ISSN:1463-9262
1463-9270
DOI:10.1039/d0gc03739g