A new metal–organic framework based on 4,4′-bibenzoic acid-2,2′-sulfone: synthesis, crystal structure and magnetic property

A new metal–organic framework (MOF), namely, {[Ni(BPS)(4,4′-bipy)] n }, (BPS = 4,4′-bibenzoic acid-2,2′-sulfone, bipy = 4,4-Bipyridine) ( 1 ), with 3D framework has been synthesized under solvothermal condition and characterized by single crystal X-ray diffraction, PXRD, TGA, FT-IR and SQUID magneto...

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Bibliographic Details
Published in:Journal of porous materials 2021-04, Vol.28 (2), p.481-486
Main Authors: Xu, Shixian, Chen, Xi, Qi, Li, Zhu, Feng, Liu, Linhai, Quan, Lixia, Hu, Jiurong, Zhong, Ming
Format: Article
Language:English
Subjects:
Catalysis
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Crystal structure
Crystals
Ferromagnetism
Magnetic measurement
Magnetic properties
Metal-organic frameworks
Nickel
Physical Chemistry
Single crystals
Superconducting quantum interference devices
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Summary:A new metal–organic framework (MOF), namely, {[Ni(BPS)(4,4′-bipy)] n }, (BPS = 4,4′-bibenzoic acid-2,2′-sulfone, bipy = 4,4-Bipyridine) ( 1 ), with 3D framework has been synthesized under solvothermal condition and characterized by single crystal X-ray diffraction, PXRD, TGA, FT-IR and SQUID magnetometry. Topological analysis indicates that 1 is a 3D (3,5)-connected framework with the short point symbol of (6 3 )(6 7 ·8 3 ). The magnetic experiments reveal that 1 exhibits typical ferromagnetic exchange in Ni(II) ions.
ISSN:1380-2224
1573-4854
DOI:10.1007/s10934-020-01002-y