Photocatalyzed cross-dehydrogenative coupling of silanes with alcohols and water

An efficient method for the dehydrogenative coupling of silanes with alcohols under photocatalysis was developed. The reaction proceeded in the presence of Ru(bpy) 3 Cl 2 (0.5 mol%) under visible light irradiation in acetonitrile at room temperature. The developed methodology was also applicable for...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2021-04, Vol.57 (3), p.366-3663
Main Authors: Lv, Haiping, Laishram, Ronibala Devi, Chen, Jingchao, Khan, Ruhima, Zhu, Yuanbin, Wu, Shiyuan, Zhang, Jianqiang, Liu, Xingyuan, Fan, Baomin
Format: Article
Language:English
Subjects:
Acetonitrile
Alcohols
Coupling
Dehydrogenation
Light irradiation
Room temperature
Silanes
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Summary:An efficient method for the dehydrogenative coupling of silanes with alcohols under photocatalysis was developed. The reaction proceeded in the presence of Ru(bpy) 3 Cl 2 (0.5 mol%) under visible light irradiation in acetonitrile at room temperature. The developed methodology was also applicable for the synthesis of silanols using water as a coupling partner. An efficient method for the dehydrogenative coupling of silanes with alcohols under photocatalysis was developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc00129a