Synthesis of TiO2 and ZnO Nanoparticles and CTAB-Stabilized Fe3O4 nanocomposite: kinetics and thermodynamics of adsorption

• Published in: Research on chemical intermediates 2021-05, Vol.47 (5), p.1759-1774
• Main Authors: Rezaei-Aghdam, Elnaz, Shamel, Ali, Khodadadi-Moghaddam, Mohammad, Ebrahimzadeh Rajaei, Gholamreza, Mohajeri, Sahar
• Format: Article
• Language: English
• Subjects: Adsorption; Aqueous solutions; Catalysis; Chemistry; Chemistry and Materials Science; Dyes; Electron microscopy; Endothermic reactions; Enthalpy; Fourier transforms; Gibbs free energy; Infrared spectroscopy; Inorganic Chemistry; Iron oxides; Isotherms; Mathematical models; Metal oxides; Microscopy; Nanocomposites; Nanomaterials; Nanoparticles; Parameters; Physical Chemistry; Spectrum analysis; Surface area; Surface chemistry; Synthesis; Titanium dioxide; Zinc oxide
• ISSN: 0922-6168; 1568-5675
• DOI: 10.1007/s11164-020-04363-w

In the present study, TiO 2 , ZnO, and CTAB-stabilized Fe 3 O 4 nanocomposite were successfully synthesized and employed for the removal of yellow 145 dye from aqueous solutions. These nanomaterials were characterized by various techniques such as X-ray diffraction spectroscopy (XRD), Fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and N 2 adsorptions/desorption isotherms (BET). The surface area of the nanocomposite was achieved 123.76 m 2  g −1 which is greater than both of TiO 2 (50.12 m 2  g −1 ) and ZnO (26.85 m 2  g −1 ). To achieve high adsorption capacity, the effects of different operational parameters such as dye concentration, pH, dose of adsorbent (TiO 2 , ZnO, and nanocomposite), and contact time were separately specified. According to the results, the pseudo-second-order kinetic model was showed better agreement with the experimental data. The rate constant ( k 2 ; g mg −1  min −1 ) for the adsorption of yellow 145 on the synthesized TiO 2 , ZnO, and nanocomposite was measured 0.0279, 0.0282, and 0.0162, respectively. Gibbs free energy, enthalpy, and entropy were calculated as the thermodynamic parameters which indicated that the adsorption process is endothermic and spontaneous. Also, the equilibrium data were fitted on Langmuir, Freundlich, Temkin, and Dobinin–Radoskovich equilibrium isotherm models. Accordingly, Longmuir and Freundlich models were the best isothermal models for describing the adsorption of yellow 145 dye by nanocomposite and metal oxides, respectively. Moreover, the results showed that the adsorption capacity depends on the specific surface area. For this reason, the adsorption capacity of nanocomposites is higher than both of TiO 2 and ZnO.