Influence of activator type on reaction kinetics, setting time, and compressive strength of alkali-activated mineral wools

• Published in: Journal of thermal analysis and calorimetry 2021-05, Vol.144 (4), p.1129-1138
• Main Authors: Yliniemi, J., Walkley, B., Provis, J. L., Kinnunen, P., Illikainen, M.
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Carbonates; Caustic soda; Chemical composition; Chemical reaction, Rate of; Chemistry; Chemistry and Materials Science; Compressive strength; Glass wool; Hydroxides; Inorganic Chemistry; Measurement Science and Instrumentation; Mineral wool; Physical Chemistry; Polymer Sciences; Reaction kinetics; Setting (hardening); Sodium; Sodium aluminate; Sodium carbonate; Sodium hydroxide; Sodium silicates; Stone
• ISSN: 1388-6150; 1588-2926
• DOI: 10.1007/s10973-020-09651-6

Alkali activation is a promising utilisation route for mineral wool wastes, due to suitable chemical composition, high reactivity, and surface area. One key factor in the development of alkali-activated binders is the selection of the suitable alkali activator. Here, the effect of sodium hydroxide, sodium silicate, sodium aluminate, and sodium carbonate solution on the alkali-activation kinetics of two main types of mineral wools, stone wool and glass wool, is investigated. Setting time and compressive strength development results are presented, which are explained and discussed in the context of isothermal calorimeter data obtained at temperature of 40 °C. Sodium hydroxide and sodium silicate solutions provided fast reaction with both mineral wools, evidenced by high heat release, high early strength, and fast setting. The reaction with sodium aluminate solution took several days to initiate, but it produced high compressive strength after 28 days of curing with both mineral wools. Glass wool reacted and hardened rapidly with sodium carbonate solution, but stone wool reacted slowly with sodium carbonate and exhibited a low extent of reaction, likely due to lower extent of reaction of stone wool under less alkaline conditions. These results show that mineral wool alkali activation kinetics and binder gel formation are controlled by the activator type and highlight the importance of choosing the most appropriate activator for each desired application.