Electrodeposition of B, Ni co‐doped diamond‐like carbon films on AZ91D magnesium alloy: Corrosion and wear resistance

• Published in: Materials and corrosion 2021-05, Vol.72 (5), p.912-924
• Main Authors: Ma, Min, Sun, Wan‐Chang, Dong, Ya‐Ru, Zhang, Ya‐Gang, Liu, Yu‐Wan, Tian, Sha‐Sha, Xiao, Yan
• Format: Article
• Language: English
• Subjects: Carbon; Coefficient of friction; Corrosion currents; Corrosion potential; Corrosion resistance; Corrosion resistant alloys; Corrosive wear; co‐doped DLC composite films; Diamond films; Diamond-like carbon films; Diamonds; Electrodeposition; electrophoretic deposition; friction and wear behavior; Magnesium alloys; Magnesium base alloys; Microhardness; Morphology; Nickel; Wear resistance
• ISSN: 0947-5117; 1521-4176
• DOI: 10.1002/maco.202012130

Diamond‐like carbon (DLC) possesses brilliant and excellent properties, including excellent corrosion resistance as well as outstanding wear resistance. Ni and B co‐doped DLC films were deposited on AZ91D magnesium alloy by electrodeposition under mild conditions (300 V and 25°C). Uniform and dense morphology of co‐doped DLC films were observed, and Ni and B were uniformly incorporated into the carbon‐based films. Among all the electrodeposits, the appearance of D and G peaks near 1330 and 1570 cm−1 revealed that the as‐deposited films were typical DLC films. As the addition of Ni was increased to 0.05 g, the highest microindentation hardness, the lowest friction coefficient, and wear loss were achieved to be 164.5 HV, 0.3, and 0.6 × 10−5 kg/m, respectively. The amorphous carbon films fabricated at 0.05 g Ni had the lowest corrosion current density and the most positive corrosion potential, which was mainly due to the small and dense granular structure effectively hindering the penetration of corrosion media. The B, Ni co‐doped diamond‐like carbon films prepared by low‐temperature liquid‐phase electrophoretic deposition on AZ91D magnesium alloys have better wear and corrosion resistance. In 3.5 wt% NaCl solution, the self‐corrosion potentials of the magnesium alloys‐coated diamond‐like carbon composite films were more positive than that of the bare magnesium alloy. Especially, the corrosion resistance was optimal when the Ni doping amount was 0.05 g/350 ml.