Synthesis of layered copper selenide on reduced graphene oxide sheets via SILAR method for flexible asymmetric solid-state supercapacitor

• Published in: Journal of alloys and compounds 2021-07, Vol.869, p.159198, Article 159198
• Main Authors: Malavekar, D.B., Bulakhe, R.N., Kale, S.B., Patil, U.M., In, Insik, Lokhande, C.D.
• Format: Article
• Language: English
• Subjects: Asymmetry; Bending machines; Computer storage devices; Copper selenide; Copper selenides; Copper sulfides; Electrode materials; Energy storage; Field emission microscopy; Flexible asymmetric supercapacitor; Graphene; Light emitting diodes; Nanoparticles; Portable equipment; Reduced graphene oxide; Sheets; Solid state; Storage systems; Successive ionic layer adsorption and reaction method; Supercapacitors
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2021.159198

Along with growing use of electrochemical energy storage systems, there is a requirement for investigating electrode materials which assure applications in portable and wearable electrical energy storage devices. In this study, facile successive ionic layer adsorption and reaction (SILAR) method was employed to composite CuSe2 with reduced graphene oxide (rGO). The X-ray diffraction study showed orientation of CuSe2 nanoparticles from (200) to (221) plane with rGO composition. The field emission-scanning electron microscope images showed that CuSe2 nanoparticles are uniformly anchored onto the surface of rGO sheets. The composite CuSe2@rGO material offered a higher specific surface area (84 m2 g−1) compared to CuSe2 (24 m2 g−1) with the specific capacitance (Cs) of 612 F g−1 at a scan rate of 2 mV s−1. Moreover, the flexible solid-state asymmetric supercapacitor (ASC) fabricated with configuration CuSe2@rGO/PVA-KOH/CuS exhibited specific energy of 28.3 Wh kg−1 at the specific power of 1538 W kg−1. The device retained about 89% of the initial Cs at a bending angle of 165°. For practical manifestation, two series connected ASC devices charged with 2.8 V delivered 19.6 mW cm−2 of initial power and illuminated LED panel made of 211 red LED’s for 150 s [Display omitted] •Copper selenide is composited with reduced graphene oxide using facile successive ionic layer adsorption and reaction method.•The hybridization with rGO significantly affects crystal growth and surface morphology of CuSe2 thin film.•Hybrid CuSe2@rGO electrode exhibits maximum specific capacitance of 612 F g−1 at a scan rate of 2 mV s−1 calculated from CV analysis.•Flexible asymmetric supercapacitor CuSe2@rGO//CuS delivers specific energy of 28.3 Wh kg-1 at specific power of 1538 W kg-1.