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Structural, electrical and electrochemical studies of ionic liquid-based polymer gel electrolyte using magnesium salt for supercapacitor application
In the present studies, the effect of ionic liquid 1-Ethyl-2,3-dimethylimidazoliumtetrafluoroborate (EDiMIM)(BF 4 ) on ionic conductivity of gel polymer electrolyte using poly(vinylidene fluoride-co-hexafluoropropylene) [PVdF(HFP)] and magnesium perchlorate [Mg(ClO 4 ) 2 ] as salt was investigated....
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| Published in: | Journal of polymer research 2021-07, Vol.28 (7), Article 235 |
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| Language: | English |
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| container_issue | 7 |
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| container_title | Journal of polymer research |
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| creator | Gupta, Ashish Jain, Amrita Tripathi, S. K. |
| description | In the present studies, the effect of ionic liquid 1-Ethyl-2,3-dimethylimidazoliumtetrafluoroborate (EDiMIM)(BF
4
) on ionic conductivity of gel polymer electrolyte using poly(vinylidene fluoride-co-hexafluoropropylene) [PVdF(HFP)] and magnesium perchlorate [Mg(ClO
4
)
2
] as salt was investigated. The maximum room temperature ionic conductivity for the optimized system was found to be of the order of 8.4 × 10
–3
S cm
−1
. The optimized composition reflects Vogel-Tammann-Fulcher (VTF) behavior in the temperature range of 25 °C to 100 °C. The X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy studies confirm the uniform blending of ionic liquid, polymer, and salts along with the enhanced amorphous nature of the optimized system. Dielectric and modulus spectra studies provide the information of electrode polarization as well as dipole relaxation properties of polymeric materials. The optimized electrolyte system possesses a sufficiently large electrochemical window of the order of 6.0 V with stainless steel electrodes. |
| doi_str_mv | 10.1007/s10965-021-02597-9 |
| format | article |
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4
) on ionic conductivity of gel polymer electrolyte using poly(vinylidene fluoride-co-hexafluoropropylene) [PVdF(HFP)] and magnesium perchlorate [Mg(ClO
4
)
2
] as salt was investigated. The maximum room temperature ionic conductivity for the optimized system was found to be of the order of 8.4 × 10
–3
S cm
−1
. The optimized composition reflects Vogel-Tammann-Fulcher (VTF) behavior in the temperature range of 25 °C to 100 °C. The X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy studies confirm the uniform blending of ionic liquid, polymer, and salts along with the enhanced amorphous nature of the optimized system. Dielectric and modulus spectra studies provide the information of electrode polarization as well as dipole relaxation properties of polymeric materials. The optimized electrolyte system possesses a sufficiently large electrochemical window of the order of 6.0 V with stainless steel electrodes.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-021-02597-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Dipoles ; Electrode polarization ; Electrolytes ; Fourier transforms ; Industrial Chemistry/Chemical Engineering ; Ion currents ; Ionic liquids ; Ions ; Magnesium perchlorates ; Original Paper ; Polymer gels ; Polymer Sciences ; Polymers ; Room temperature ; Spectrum analysis ; Stainless steels ; Vinylidene ; Vinylidene fluoride</subject><ispartof>Journal of polymer research, 2021-07, Vol.28 (7), Article 235</ispartof><rights>The Author(s) 2021</rights><rights>The Author(s) 2021. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c466t-471e36771f2563bdcadcf938d575fe8da0ec5fe105be215f2a8a4d0f91f3a7423</citedby><cites>FETCH-LOGICAL-c466t-471e36771f2563bdcadcf938d575fe8da0ec5fe105be215f2a8a4d0f91f3a7423</cites><orcidid>0000-0002-3347-1162 ; 0000-0001-7657-8974</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Gupta, Ashish</creatorcontrib><creatorcontrib>Jain, Amrita</creatorcontrib><creatorcontrib>Tripathi, S. K.</creatorcontrib><title>Structural, electrical and electrochemical studies of ionic liquid-based polymer gel electrolyte using magnesium salt for supercapacitor application</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>In the present studies, the effect of ionic liquid 1-Ethyl-2,3-dimethylimidazoliumtetrafluoroborate (EDiMIM)(BF
4
) on ionic conductivity of gel polymer electrolyte using poly(vinylidene fluoride-co-hexafluoropropylene) [PVdF(HFP)] and magnesium perchlorate [Mg(ClO
4
)
2
] as salt was investigated. The maximum room temperature ionic conductivity for the optimized system was found to be of the order of 8.4 × 10
–3
S cm
−1
. The optimized composition reflects Vogel-Tammann-Fulcher (VTF) behavior in the temperature range of 25 °C to 100 °C. The X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy studies confirm the uniform blending of ionic liquid, polymer, and salts along with the enhanced amorphous nature of the optimized system. Dielectric and modulus spectra studies provide the information of electrode polarization as well as dipole relaxation properties of polymeric materials. The optimized electrolyte system possesses a sufficiently large electrochemical window of the order of 6.0 V with stainless steel electrodes.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dipoles</subject><subject>Electrode polarization</subject><subject>Electrolytes</subject><subject>Fourier transforms</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ion currents</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Magnesium perchlorates</subject><subject>Original Paper</subject><subject>Polymer gels</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Room temperature</subject><subject>Spectrum analysis</subject><subject>Stainless steels</subject><subject>Vinylidene</subject><subject>Vinylidene fluoride</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9UMlKBDEQbUTBcfkBTwGvtmaZdLqPMriB4EE9h0xSGTOkl8lymP_wg40zijcPRdUr3gKvqi4IviYYi5tIcNfwGlNShnei7g6qGeGC1m3H-GG5MaV1Jxp8XJ3EuMaYc9G0s-rzNYWsUw7KXyHwoFNwWnmkBvMDR_0B_e4XUzYOIhotcuPgNPJuk52plyqCQdPotz0EtAL_q_TbBChHN6xQr1YDRJd7FJVPyI4BxTxB0GpS2qUC1TT5EpOK9Vl1ZJWPcP6zT6v3-7u3xWP9_PLwtLh9rvW8aVI9FwRYIwSxlDdsabQy2nasNVxwC61RGHQ5COZLoIRbqlo1N9h2xDIl5pSdVpd73ymMmwwxyfWYw1AiJeWs4YyKlhUW3bN0GGMMYOUUXK_CVhIsv9uX-_ZlaV_u2pddEbG9KBbysILwZ_2P6gv6Coy1</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Gupta, Ashish</creator><creator>Jain, Amrita</creator><creator>Tripathi, S. K.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3347-1162</orcidid><orcidid>https://orcid.org/0000-0001-7657-8974</orcidid></search><sort><creationdate>20210701</creationdate><title>Structural, electrical and electrochemical studies of ionic liquid-based polymer gel electrolyte using magnesium salt for supercapacitor application</title><author>Gupta, Ashish ; Jain, Amrita ; Tripathi, S. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c466t-471e36771f2563bdcadcf938d575fe8da0ec5fe105be215f2a8a4d0f91f3a7423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dipoles</topic><topic>Electrode polarization</topic><topic>Electrolytes</topic><topic>Fourier transforms</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ion currents</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Magnesium perchlorates</topic><topic>Original Paper</topic><topic>Polymer gels</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Room temperature</topic><topic>Spectrum analysis</topic><topic>Stainless steels</topic><topic>Vinylidene</topic><topic>Vinylidene fluoride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gupta, Ashish</creatorcontrib><creatorcontrib>Jain, Amrita</creatorcontrib><creatorcontrib>Tripathi, S. K.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gupta, Ashish</au><au>Jain, Amrita</au><au>Tripathi, S. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural, electrical and electrochemical studies of ionic liquid-based polymer gel electrolyte using magnesium salt for supercapacitor application</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>28</volume><issue>7</issue><artnum>235</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>In the present studies, the effect of ionic liquid 1-Ethyl-2,3-dimethylimidazoliumtetrafluoroborate (EDiMIM)(BF
4
) on ionic conductivity of gel polymer electrolyte using poly(vinylidene fluoride-co-hexafluoropropylene) [PVdF(HFP)] and magnesium perchlorate [Mg(ClO
4
)
2
] as salt was investigated. The maximum room temperature ionic conductivity for the optimized system was found to be of the order of 8.4 × 10
–3
S cm
−1
. The optimized composition reflects Vogel-Tammann-Fulcher (VTF) behavior in the temperature range of 25 °C to 100 °C. The X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy studies confirm the uniform blending of ionic liquid, polymer, and salts along with the enhanced amorphous nature of the optimized system. Dielectric and modulus spectra studies provide the information of electrode polarization as well as dipole relaxation properties of polymeric materials. The optimized electrolyte system possesses a sufficiently large electrochemical window of the order of 6.0 V with stainless steel electrodes.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-021-02597-9</doi><orcidid>https://orcid.org/0000-0002-3347-1162</orcidid><orcidid>https://orcid.org/0000-0001-7657-8974</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Dipoles Electrode polarization Electrolytes Fourier transforms Industrial Chemistry/Chemical Engineering Ion currents Ionic liquids Ions Magnesium perchlorates Original Paper Polymer gels Polymer Sciences Polymers Room temperature Spectrum analysis Stainless steels Vinylidene Vinylidene fluoride |
| title | Structural, electrical and electrochemical studies of ionic liquid-based polymer gel electrolyte using magnesium salt for supercapacitor application |
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