Composite Materials Manufactured by Photopolymer 3D Printing with Metal-Organic Frameworks

New composite materials containing metal-organic framework (MOF-5) particles were manufactured by 3D printing. The optimal composition of the photopolymer formulation and printing conditions ensuring the highest quality of printing were selected. Retention of the metal-organic framework (MOF) struct...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2021-05, Vol.47 (5), p.319-325
Main Authors: Cherevko, A. I., Denisov, G. L., Nikovskii, I. A., Polezhaev, A. V., Korlyukov, A. A., Novikov, V. V.
Format: Article
Language:English
Subjects:
3-D printers
Chemical reactions
Chemistry
Chemistry and Materials Science
Composite materials
Computed tomography
Inorganic Chemistry
Metal-organic frameworks
Particulate composites
Photopolymers
Physical Chemistry
Three dimensional printing
X ray powder diffraction
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Summary:New composite materials containing metal-organic framework (MOF-5) particles were manufactured by 3D printing. The optimal composition of the photopolymer formulation and printing conditions ensuring the highest quality of printing were selected. Retention of the metal-organic framework (MOF) structure in the resulting composite objects was demonstrated by powder X-ray diffraction. The distribution of MOF-5 particles over the whole bulk of the 3D product was studied by X-ray computed tomography. In the future, composite materials of this type containing catalytically active MOFs, with their structure and properties being controllable at the micro and macro levels, could find application as catalysts of various chemical processes.
ISSN:1070-3284
1608-3318
DOI:10.1134/S107032842105002X