Quantification, distribution, and effects of di (2‐ethylhexyl) phthalate contamination: Risk analysis and mitigation strategies in urban environment

• Published in: Water environment research 2021-06, Vol.93 (6), p.940-952
• Main Authors: Shivaraju, Harikaranahalli Puttaiah, Yashas, Shivamurthy Ravindra, Harini, Revanna
• Format: Article
• Language: English
• Subjects: Aquatic organisms; Chromatography; Contaminants; Contamination; di(2‐ethylhexyl) phthalate (DEHP); Dioctyl phthalate; Distribution; emerging contaminants; Environmental management; Environmental risk; Gas chromatography; Groundwater; Groundwater treatment; Health risks; management strategies; Mitigation; Municipal wastewater; Phthalates; Quotients; Risk analysis; risk assessment; risk quotient method; Risk reduction; Sediments; Surface water; Transport; Urban areas; Urban environments; Wastewater; Wastewater treatment; Water analysis; water quality; Water sampling
• ISSN: 1061-4303; 1554-7531
• DOI: 10.1002/wer.1486

Phthalate acid ester, di (2‐ethylhexyl) phthalate (DEHP) is ubiquitously detected contaminant of emerging concerns (CECs) in all the environmental samples. The present study attempted to understand the fate and transport of DEHP in urban areas by evaluating the quantities, distribution, risk, and effects in the Mysuru city, India. The study is anticipated to serve as a vital document for local and national regulators to frame a robust DEHP management plan and mitigate the risks associated. Liquid–liquid microextraction followed by gas chromatographic analysis was adopted to determine the concentrations of DEHP. The risk quotient method was adopted to assess potential risk, and a conceptual planning model framework was designed to mitigate the DEHP contamination. The municipal wastewater contained 115 ± 9.2 μg/L, whereas treated municipal wastewater showed 95 ± 7.6 μg/L DEHP that was attributed to the inefficiency of the treatment plant. Further, sediments in surface water, as well as groundwater samples of the study area, showed 8 ± 0.64 to 12 ± 0.96 μg/L and 32 ± 2.56 to 40 ± 3.2 μg/kg of DEHP, respectively. The risk quotient of 19.17 for samples in around treatment indicated highest risk, whereas groundwater samples had a risk quotient of 1–2 indicating relative risk to aquatic organisms. In addition, the study highlighted the source, possible entry pathways, and management strategies including treatment aspects to draw an understanding of the distribution and potential ecological imbalances with contamination of DEHP in the urban sector. Practitioner points Understand the fate and transportation of DEHP in urban wastewater. Primary investigation and assessment to possible health and environmental risks of DEHP contamination in urban wastewater. Revealed the associated health risks and proposed possible management strategies. High risks of DEHP contamination in aqueous ecosystem by municipal wastewater and associated activities which cause health and environmental risks