Eutectic iodide-based salt as a melem-to-PTI conversion stopping agent for all-in-one graphitic carbon nitride

• Published in: Applied catalysis. B, Environmental Environmental, 2021-10, Vol.294, p.120222, Article 120222
• Main Authors: Lee, Tae-Gyu, Kang, Hui-Ju, Kim, Jong-Ho, Suzuki, Norihiro, Fujishima, Akira, Choi, Minkee, Jun, Young-Si
• Format: Article
• Language: English
• Subjects: Alkali metal iodide; Alkali metals; Carbon nitride; Catalytic activity; Current carriers; Cyano functional groups; Functional groups; Graphitic carbon nitride; Hydrogen evolution reactions; Intermediates; Iodides; K+-coordination; Photocatalysis; Recombination; Stopping agent; Sunlight; Triazine
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2021.120222

[Display omitted] •The eutectic LiI/KI is utilized as a stopping agent for the melem-to-PTI conversion reaction.•g-CN with K+-coordinated cyano groups and triazine–tri-s-triazine electron D–A structure is achieved in a controlled manner.•The formation mechanism of all-in-one g-CN in LiI/KI is thoroughly investigated and proposed.•The resulting g-CN shows superior photocatalytic activity in HER under both sunlight and visible light irradiation. The poor absorption of visible light and rapid recombination of photoexcited charge carriers are the two main factors responsible for the low photocatalytic activities of g-CN under sunlight. To mitigate these technical challenges, we utilize molten-salt synthesis based on alkali metal iodide. The high reactivity of LiI/KI does not allow the polycondensation of triazine dicyanamide intermediates further into PTI, the degree of which depends on the initial weight ratio of eutectic mixture to molecular precursor. This enables the controlled introduction of cyano functional groups with K+-coordination and decomposition of tri-s-triazine into triazine. The resulting all-in-one g-CN-I displays a photocatalytic hydrogen evolution reaction rate of 147 and 60 μmol/h from water under visible light and sunlight, respectively, which are 76 and 7 times higher than those of bulk g-CN. This study demonstrates the significant improvement in the photocatalytic activity of g-CN achievable through the synergistic combination of structural functionalities.