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Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands
The first examples of scandium methylidyne complexes [(Cp*)Sc(μ 2 -X)] 3 (μ 3 -CH) (Cp* = C 5 Me 5 ; X = Br, Me, OMe), free of Lewis acids, can be achieved in high yields from [(Cp*)ScMe 2 ] 2 through a facile route. The chemical and geometrical flexibility to incorporate organic substrates indicate...
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| Published in: | Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (52), p.6436-6439 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c244t-98749e3f4006cb7891528db3b089368fe38e97a8a1db2e1a5f9a61e178f9d80a3 |
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| cites | cdi_FETCH-LOGICAL-c244t-98749e3f4006cb7891528db3b089368fe38e97a8a1db2e1a5f9a61e178f9d80a3 |
| container_end_page | 6439 |
| container_issue | 52 |
| container_start_page | 6436 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 57 |
| creator | Deng, Peng Shi, Xianghui Gong, Xun Cheng, Jianhua |
| description | The first examples of scandium methylidyne complexes [(Cp*)Sc(μ
2
-X)]
3
(μ
3
-CH) (Cp* = C
5
Me
5
; X = Br, Me, OMe), free of Lewis acids, can be achieved in high yields from [(Cp*)ScMe
2
]
2
through a facile route. The chemical and geometrical flexibility to incorporate organic substrates indicates a rich chemistry of complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH).
Scandium methylidyne complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH), free of Lewis acids, can be achieved in high yield, and shows the flexibility to incorporate organic substrates by insertion into the Sc-C(methylidyne) bond. |
| doi_str_mv | 10.1039/d1cc01645h |
| format | article |
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2
-X)]
3
(μ
3
-CH) (Cp* = C
5
Me
5
; X = Br, Me, OMe), free of Lewis acids, can be achieved in high yields from [(Cp*)ScMe
2
]
2
through a facile route. The chemical and geometrical flexibility to incorporate organic substrates indicates a rich chemistry of complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH).
Scandium methylidyne complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH), free of Lewis acids, can be achieved in high yield, and shows the flexibility to incorporate organic substrates by insertion into the Sc-C(methylidyne) bond.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc01645h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Coordination compounds ; Crystallography ; Methylidyne ; Scandium ; Substrates</subject><ispartof>Chemical communications (Cambridge, England), 2021-06, Vol.57 (52), p.6436-6439</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c244t-98749e3f4006cb7891528db3b089368fe38e97a8a1db2e1a5f9a61e178f9d80a3</citedby><cites>FETCH-LOGICAL-c244t-98749e3f4006cb7891528db3b089368fe38e97a8a1db2e1a5f9a61e178f9d80a3</cites><orcidid>0000-0003-0330-4846 ; 0000-0001-5476-9307</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Deng, Peng</creatorcontrib><creatorcontrib>Shi, Xianghui</creatorcontrib><creatorcontrib>Gong, Xun</creatorcontrib><creatorcontrib>Cheng, Jianhua</creatorcontrib><title>Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands</title><title>Chemical communications (Cambridge, England)</title><description>The first examples of scandium methylidyne complexes [(Cp*)Sc(μ
2
-X)]
3
(μ
3
-CH) (Cp* = C
5
Me
5
; X = Br, Me, OMe), free of Lewis acids, can be achieved in high yields from [(Cp*)ScMe
2
]
2
through a facile route. The chemical and geometrical flexibility to incorporate organic substrates indicates a rich chemistry of complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH).
Scandium methylidyne complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH), free of Lewis acids, can be achieved in high yield, and shows the flexibility to incorporate organic substrates by insertion into the Sc-C(methylidyne) bond.</description><subject>Coordination compounds</subject><subject>Crystallography</subject><subject>Methylidyne</subject><subject>Scandium</subject><subject>Substrates</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpd0UtLxDAUBeAgCo6jG_dCwY0I1aRJ2mQp42MEwc0IgouSprdOhvRh0oL115uZioLZ3Fz4OIQThE4JviKYyuuSaI1Jyvh6D80ITVnMmXjd3965jDPK-CE68n6DwyFczNDbyplm0BaUi7xWTWmGOqqhX4_WlGMDkW7rzsIn-Mj3qjDWfEEZFWPUQdOrCepR23a3lwaa0UbWvIckf4wOKmU9nPzMOXq5v1stlvHT88Pj4uYp1gljfSxFxiTQimGc6iITkvBElAUtsJA0FRVQATJTQpGySIAoXkmVEiCZqGQpsKJzdDHldq79GMD3eW28BmtVA-3g84RTgTkJuYGe_6ObdnBNeF1QjEtBscyCupyUdq33Dqq8c6ZWbswJzrc957dksdj1vAz4bMLO61_39w_0Gyaje3I</recordid><startdate>20210629</startdate><enddate>20210629</enddate><creator>Deng, Peng</creator><creator>Shi, Xianghui</creator><creator>Gong, Xun</creator><creator>Cheng, Jianhua</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0330-4846</orcidid><orcidid>https://orcid.org/0000-0001-5476-9307</orcidid></search><sort><creationdate>20210629</creationdate><title>Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands</title><author>Deng, Peng ; Shi, Xianghui ; Gong, Xun ; Cheng, Jianhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c244t-98749e3f4006cb7891528db3b089368fe38e97a8a1db2e1a5f9a61e178f9d80a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Coordination compounds</topic><topic>Crystallography</topic><topic>Methylidyne</topic><topic>Scandium</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Peng</creatorcontrib><creatorcontrib>Shi, Xianghui</creatorcontrib><creatorcontrib>Gong, Xun</creatorcontrib><creatorcontrib>Cheng, Jianhua</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Peng</au><au>Shi, Xianghui</au><au>Gong, Xun</au><au>Cheng, Jianhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-06-29</date><risdate>2021</risdate><volume>57</volume><issue>52</issue><spage>6436</spage><epage>6439</epage><pages>6436-6439</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The first examples of scandium methylidyne complexes [(Cp*)Sc(μ
2
-X)]
3
(μ
3
-CH) (Cp* = C
5
Me
5
; X = Br, Me, OMe), free of Lewis acids, can be achieved in high yields from [(Cp*)ScMe
2
]
2
through a facile route. The chemical and geometrical flexibility to incorporate organic substrates indicates a rich chemistry of complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH).
Scandium methylidyne complex [(Cp*)Sc(μ
2
-OMe)]
3
(μ
3
-CH), free of Lewis acids, can be achieved in high yield, and shows the flexibility to incorporate organic substrates by insertion into the Sc-C(methylidyne) bond.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1cc01645h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-0330-4846</orcidid><orcidid>https://orcid.org/0000-0001-5476-9307</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-06, Vol.57 (52), p.6436-6439 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_2545983097 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Coordination compounds Crystallography Methylidyne Scandium Substrates |
| title | Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands |
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