Polymorphism in a two-dimensional copper() metal-organic framework with the ligand bis(4-pyridylthio)methane

Polymorphism is a common phenomenon in crystalline materials but it has barely been studied in the field of metal organic frameworks. The study of polymorphism is useful to investigate structure-property relationships and control over the synthesis of particular polymorphs could be an effective way...

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Bibliographic Details
Published in:CrystEngComm 2021-07, Vol.23 (26), p.4658-4666
Main Authors: Gómez-Paz, Olaya, Carballo, Rosa, Lago, Ana B, Vázquez-López, Ezequiel M
Format: Article
Language:English
Subjects:
Coordination polymers
Copper chloride
Crystallography
Material properties
Metal-organic frameworks
Methane
Physical properties
Polymorphism
Thermodynamic properties
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Summary:Polymorphism is a common phenomenon in crystalline materials but it has barely been studied in the field of metal organic frameworks. The study of polymorphism is useful to investigate structure-property relationships and control over the synthesis of particular polymorphs could be an effective way to fine-tune the physical properties of materials. We report here the preparation and characterization of three polymorphs of a copper( i ) coordination polymer 2 ∞ CuCl(4bpytm), 4bpytm = bis(4-pyridylthio)methane. The structural and thermal properties of these compounds were studied to obtain a detailed knowledge of the differences between the three polymorphic forms. Study of the polymorphism observed in a copper( i ) coordination polymer with a N,N bidentate ligand.
ISSN:1466-8033
1466-8033
DOI:10.1039/d1ce00461a