Effect of Prior Oxidation on the Reduction Behavior of Magnetite-Based Iron Ore During Hydrogen-Induced Fluidized Bed Reduction

• Published in: Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2021-08, Vol.52 (4), p.1955-1971
• Main Authors: Zheng, Heng, Spreitzer, Daniel, Wolfinger, Thomas, Schenk, Johannes, Xu, Runsheng
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemical reactions; Chemistry and Materials Science; Diffusion rate; Fluidized bed reduction; Fluidized beds; Hydrogen reduction; Iron compounds; Iron ores; Magnesium oxide; Magnetite; Materials Science; Metallic Materials; Nanotechnology; Original Research Article; Oxidation; Structural Materials; Surfaces and Interfaces; Thin Films
• ISSN: 1073-5615; 1543-1916
• DOI: 10.1007/s11663-021-02215-5

Magnetite-based iron ore usually shows a high sticking tendency and a poor reducibility in the fluidized bed because of its dense structure. To enhance the fluidization and reduction behaviors of magnetite-based iron ore during hydrogen-induced fluidized bed reduction, the effect of a prior oxidation treatment is investigated. The results show that the untreated magnetite-based iron ore cannot be fluidized successfully in the tested temperature range between 600 °C and 800 °C. At 600 °C reduction temperature, the de-fluidization can be avoided by a prior oxidation treatment. At higher reduction temperatures, the fluidization behavior can be further improved by an addition of 0.5 wt pct MgO. Magnesiowüstite (Fe x Mg 1− x O) is formed, which decreases the contact chance of the sticky surface between particles. Regarding to the reduction rate, a prior partial oxidation is more beneficial compared to deep oxidation. The kinetic analysis shows that MgO could promote the initial reaction. The reaction rate limiting step is no longer diffusion but chemical reaction for prior partly oxidized samples. A prior partial oxidation combined with an addition of MgO is considered to be a promising pretreatment method for a successful processing of magnetite-based iron ore.