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Temperature Tuned Two Novel 3D Zn(II) Metal Organic Frameworks Exhibiting Luminescence Properties
Two novel porous zinc metal-organic frameworks (MOFs) 1 and 2 based on 1,1′-bis-((3,5-dicarboxybenzyl)-4,4′-bipyridinium) dichloride (H 4 bdcbpy·2Cl) ligand have been successfully synthesized by solvothermal reactions at different temperatures. Compounds 1 and 2 have the same composition but crystal...
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| Published in: | Russian journal of inorganic chemistry 2021-07, Vol.66 (7), p.982-988 |
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| Main Authors: | , , , |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c316t-b87c196f7b0178af10cb31e2eece722fe573dc8d0d87576b14cfb88e5c32fe203 |
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| container_issue | 7 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Minghui Zuo Zhou, Jian Yu, Jinhuan Cui, Shuxin |
| description | Two novel porous zinc metal-organic frameworks (MOFs)
1
and
2
based on 1,1′-bis-((3,5-dicarboxybenzyl)-4,4′-bipyridinium) dichloride (H
4
bdcbpy·2Cl) ligand have been successfully synthesized by solvothermal reactions at different temperatures. Compounds
1
and
2
have the same composition but crystallize in different crystal systems. Compound
1
synthesized at low temperature crystallizes in the monoclinic system, and compound
2
prepared at high temperature crystallizes in the rhombohedral system. The structural differences of two compounds indicate that temperature plays an important role in the formation of the Zn-based MOFs. The Zn
2+
ions are bridged by deprotonated formic acid moieties to form a 3D network in both compounds. H
4
bdcbpy·2Cl provided an acidic environment, which led to the decomposition of DMF into a rare C
3
H
2
N
2
2+
cation. Nitrogen adsorption measurement displays that the adsorption capacity of
1
is 711 m
2
g
–1
. The fluorescence spectra of compound
1
shows that there is a strong emission peak at 527 nm. |
| doi_str_mv | 10.1134/S0036023621070159 |
| format | article |
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1
and
2
based on 1,1′-bis-((3,5-dicarboxybenzyl)-4,4′-bipyridinium) dichloride (H
4
bdcbpy·2Cl) ligand have been successfully synthesized by solvothermal reactions at different temperatures. Compounds
1
and
2
have the same composition but crystallize in different crystal systems. Compound
1
synthesized at low temperature crystallizes in the monoclinic system, and compound
2
prepared at high temperature crystallizes in the rhombohedral system. The structural differences of two compounds indicate that temperature plays an important role in the formation of the Zn-based MOFs. The Zn
2+
ions are bridged by deprotonated formic acid moieties to form a 3D network in both compounds. H
4
bdcbpy·2Cl provided an acidic environment, which led to the decomposition of DMF into a rare C
3
H
2
N
2
2+
cation. Nitrogen adsorption measurement displays that the adsorption capacity of
1
is 711 m
2
g
–1
. The fluorescence spectra of compound
1
shows that there is a strong emission peak at 527 nm.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023621070159</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorption ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coordination Compounds ; Dichlorides ; Fluorescence ; Formic acid ; High temperature ; Inorganic Chemistry ; Low temperature ; Luminescence ; Metal-organic frameworks ; Optical properties ; Zinc</subject><ispartof>Russian journal of inorganic chemistry, 2021-07, Vol.66 (7), p.982-988</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2021, Vol. 66, No. 7, pp. 982–988. © Pleiades Publishing, Ltd., 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-b87c196f7b0178af10cb31e2eece722fe573dc8d0d87576b14cfb88e5c32fe203</citedby><cites>FETCH-LOGICAL-c316t-b87c196f7b0178af10cb31e2eece722fe573dc8d0d87576b14cfb88e5c32fe203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Minghui Zuo</creatorcontrib><creatorcontrib>Zhou, Jian</creatorcontrib><creatorcontrib>Yu, Jinhuan</creatorcontrib><creatorcontrib>Cui, Shuxin</creatorcontrib><title>Temperature Tuned Two Novel 3D Zn(II) Metal Organic Frameworks Exhibiting Luminescence Properties</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Two novel porous zinc metal-organic frameworks (MOFs)
1
and
2
based on 1,1′-bis-((3,5-dicarboxybenzyl)-4,4′-bipyridinium) dichloride (H
4
bdcbpy·2Cl) ligand have been successfully synthesized by solvothermal reactions at different temperatures. Compounds
1
and
2
have the same composition but crystallize in different crystal systems. Compound
1
synthesized at low temperature crystallizes in the monoclinic system, and compound
2
prepared at high temperature crystallizes in the rhombohedral system. The structural differences of two compounds indicate that temperature plays an important role in the formation of the Zn-based MOFs. The Zn
2+
ions are bridged by deprotonated formic acid moieties to form a 3D network in both compounds. H
4
bdcbpy·2Cl provided an acidic environment, which led to the decomposition of DMF into a rare C
3
H
2
N
2
2+
cation. Nitrogen adsorption measurement displays that the adsorption capacity of
1
is 711 m
2
g
–1
. The fluorescence spectra of compound
1
shows that there is a strong emission peak at 527 nm.</description><subject>Adsorption</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination Compounds</subject><subject>Dichlorides</subject><subject>Fluorescence</subject><subject>Formic acid</subject><subject>High temperature</subject><subject>Inorganic Chemistry</subject><subject>Low temperature</subject><subject>Luminescence</subject><subject>Metal-organic frameworks</subject><subject>Optical properties</subject><subject>Zinc</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAURS0EEqXwA9gsscAQ8Ivjj46otFCpUCTCwhI5zktJaZ1iJxT-PamKxICY3nDPPU-6hJwCuwTgydUTY1yymMsYmGIgBnukB4JDpCXwfdLbxtE2PyRHISwYSxKmdI-YFFdr9KZpPdK0dVjQdFPTh_oDl5Tf0Bd3Pplc0HtszJLO_Ny4ytKxNyvc1P4t0NHna5VXTeXmdNquKofBorNIH33daZsKwzE5KM0y4MnP7ZPn8Sgd3kXT2e1keD2NLAfZRLlWFgayVDkDpU0JzOYcMEa0qOK4RKF4YXXBCq2Ekjkktsy1RmF5F8aM98nZzrv29XuLockWdetd9zKLhWBSahiIjoIdZX0dgscyW_tqZfxXBizbLpn9WbLrxLtO6Fg3R_9r_r_0Da-XdMQ</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Minghui Zuo</creator><creator>Zhou, Jian</creator><creator>Yu, Jinhuan</creator><creator>Cui, Shuxin</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210701</creationdate><title>Temperature Tuned Two Novel 3D Zn(II) Metal Organic Frameworks Exhibiting Luminescence Properties</title><author>Minghui Zuo ; Zhou, Jian ; Yu, Jinhuan ; Cui, Shuxin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-b87c196f7b0178af10cb31e2eece722fe573dc8d0d87576b14cfb88e5c32fe203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination Compounds</topic><topic>Dichlorides</topic><topic>Fluorescence</topic><topic>Formic acid</topic><topic>High temperature</topic><topic>Inorganic Chemistry</topic><topic>Low temperature</topic><topic>Luminescence</topic><topic>Metal-organic frameworks</topic><topic>Optical properties</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Minghui Zuo</creatorcontrib><creatorcontrib>Zhou, Jian</creatorcontrib><creatorcontrib>Yu, Jinhuan</creatorcontrib><creatorcontrib>Cui, Shuxin</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Minghui Zuo</au><au>Zhou, Jian</au><au>Yu, Jinhuan</au><au>Cui, Shuxin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature Tuned Two Novel 3D Zn(II) Metal Organic Frameworks Exhibiting Luminescence Properties</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>66</volume><issue>7</issue><spage>982</spage><epage>988</epage><pages>982-988</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Two novel porous zinc metal-organic frameworks (MOFs)
1
and
2
based on 1,1′-bis-((3,5-dicarboxybenzyl)-4,4′-bipyridinium) dichloride (H
4
bdcbpy·2Cl) ligand have been successfully synthesized by solvothermal reactions at different temperatures. Compounds
1
and
2
have the same composition but crystallize in different crystal systems. Compound
1
synthesized at low temperature crystallizes in the monoclinic system, and compound
2
prepared at high temperature crystallizes in the rhombohedral system. The structural differences of two compounds indicate that temperature plays an important role in the formation of the Zn-based MOFs. The Zn
2+
ions are bridged by deprotonated formic acid moieties to form a 3D network in both compounds. H
4
bdcbpy·2Cl provided an acidic environment, which led to the decomposition of DMF into a rare C
3
H
2
N
2
2+
cation. Nitrogen adsorption measurement displays that the adsorption capacity of
1
is 711 m
2
g
–1
. The fluorescence spectra of compound
1
shows that there is a strong emission peak at 527 nm.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023621070159</doi><tpages>7</tpages></addata></record> |
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| issn | 0036-0236 1531-8613 |
| language | eng |
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| subjects | Adsorption Chemical synthesis Chemistry Chemistry and Materials Science Coordination Compounds Dichlorides Fluorescence Formic acid High temperature Inorganic Chemistry Low temperature Luminescence Metal-organic frameworks Optical properties Zinc |
| title | Temperature Tuned Two Novel 3D Zn(II) Metal Organic Frameworks Exhibiting Luminescence Properties |
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