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Influence of Isostructural Substitution of Gadolinium By Europium(III) on the Luminescent Properties of K3Gd(PO4)2:Eu
Solid solutions of K 3 Gd(PO 4 ) 2 :Eu containing 0.1 to 10 mole % of europium(III) were obtained by solid-phase interaction. The obtained micropowders were characterized by X-ray phase analysis, IR, and luminescence spectroscopy. It is shown that doping does not affect the symmetry of the double ph...
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Published in: | Theoretical and experimental chemistry 2021-05, Vol.57 (2), p.121-125 |
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container_end_page | 125 |
container_issue | 2 |
container_start_page | 121 |
container_title | Theoretical and experimental chemistry |
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creator | Terebilenko, K. V. Chornii, V. P. Lysenko, A. V. Petrenko, O. V. Nedilko, S. G. Slobodyanik, M. S. |
description | Solid solutions of K
3
Gd(PO
4
)
2
:Eu containing 0.1 to 10 mole % of europium(III) were obtained by solid-phase interaction. The obtained micropowders were characterized by X-ray phase analysis, IR, and luminescence spectroscopy. It is shown that doping does not affect the symmetry of the double phosphate framework. All studied samples are characterized by intense red photoluminescence at room temperature, which is associated with the
5
D
0
→
7
F
0-4
radiation transitions in Eu
3+
ions. The absence of concentration attenuation and color characteristics of the samples indicate the prospects of using the K
3
Gd
0.9
Eu
0.1
(PO
4
)
2
compound as a red phosphor. |
doi_str_mv | 10.1007/s11237-021-09680-8 |
format | article |
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3
Gd(PO
4
)
2
:Eu containing 0.1 to 10 mole % of europium(III) were obtained by solid-phase interaction. The obtained micropowders were characterized by X-ray phase analysis, IR, and luminescence spectroscopy. It is shown that doping does not affect the symmetry of the double phosphate framework. All studied samples are characterized by intense red photoluminescence at room temperature, which is associated with the
5
D
0
→
7
F
0-4
radiation transitions in Eu
3+
ions. The absence of concentration attenuation and color characteristics of the samples indicate the prospects of using the K
3
Gd
0.9
Eu
0.1
(PO
4
)
2
compound as a red phosphor.</description><identifier>ISSN: 0040-5760</identifier><identifier>EISSN: 1573-935X</identifier><identifier>DOI: 10.1007/s11237-021-09680-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Attenuation ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Europium ; Gadolinium ; Infrared analysis ; Infrared spectroscopy ; Luminescence ; Optical properties ; Phosphors ; Photoluminescence ; Room temperature ; Solid phases ; Solid solutions</subject><ispartof>Theoretical and experimental chemistry, 2021-05, Vol.57 (2), p.121-125</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2348-1dfd503ff60e180c04b9f973cd60d72d6a0061f12bc3581850a365d22cdf92e3</citedby><cites>FETCH-LOGICAL-c2348-1dfd503ff60e180c04b9f973cd60d72d6a0061f12bc3581850a365d22cdf92e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Terebilenko, K. V.</creatorcontrib><creatorcontrib>Chornii, V. P.</creatorcontrib><creatorcontrib>Lysenko, A. V.</creatorcontrib><creatorcontrib>Petrenko, O. V.</creatorcontrib><creatorcontrib>Nedilko, S. G.</creatorcontrib><creatorcontrib>Slobodyanik, M. S.</creatorcontrib><title>Influence of Isostructural Substitution of Gadolinium By Europium(III) on the Luminescent Properties of K3Gd(PO4)2:Eu</title><title>Theoretical and experimental chemistry</title><addtitle>Theor Exp Chem</addtitle><description>Solid solutions of K
3
Gd(PO
4
)
2
:Eu containing 0.1 to 10 mole % of europium(III) were obtained by solid-phase interaction. The obtained micropowders were characterized by X-ray phase analysis, IR, and luminescence spectroscopy. It is shown that doping does not affect the symmetry of the double phosphate framework. All studied samples are characterized by intense red photoluminescence at room temperature, which is associated with the
5
D
0
→
7
F
0-4
radiation transitions in Eu
3+
ions. The absence of concentration attenuation and color characteristics of the samples indicate the prospects of using the K
3
Gd
0.9
Eu
0.1
(PO
4
)
2
compound as a red phosphor.</description><subject>Attenuation</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Europium</subject><subject>Gadolinium</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Luminescence</subject><subject>Optical properties</subject><subject>Phosphors</subject><subject>Photoluminescence</subject><subject>Room temperature</subject><subject>Solid phases</subject><subject>Solid solutions</subject><issn>0040-5760</issn><issn>1573-935X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wNOCl3pYnSSbbNablloXCy3Yg7ewzYduaXdrPg7996ZW8OZpBuZ53oEXoWsMdxigvPcYE1rmQHAOFReQixM0wKykeUXZ-ykaABSQs5LDObrwfg2QNAEDFOvObqLplMl6m9W-98FFFaJrNtlbXPnQhhjavjtcp43uN23Xxm32tM8m0fW7tI_qur7NEhE-TTaL27YzXpkuZIt0Ny60xh_kVzrVo8W8uCUPk3iJzmyz8ebqdw7R8nmyHL_ks_m0Hj_OckVoIXKsrWZAreVgsAAFxaqyVUmV5qBLonkDwLHFZKUoE1gwaChnmhClbUUMHaKbY-zO9V_R-CDXfXRd-igJY1zwUtAyUeRIKdd774yVO9duG7eXGOShXXlsV6Z25U-7UiSJHiWf4O7DuL_of6xvUMF8bg</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Terebilenko, K. V.</creator><creator>Chornii, V. P.</creator><creator>Lysenko, A. V.</creator><creator>Petrenko, O. V.</creator><creator>Nedilko, S. G.</creator><creator>Slobodyanik, M. S.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210501</creationdate><title>Influence of Isostructural Substitution of Gadolinium By Europium(III) on the Luminescent Properties of K3Gd(PO4)2:Eu</title><author>Terebilenko, K. V. ; Chornii, V. P. ; Lysenko, A. V. ; Petrenko, O. V. ; Nedilko, S. G. ; Slobodyanik, M. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2348-1dfd503ff60e180c04b9f973cd60d72d6a0061f12bc3581850a365d22cdf92e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Attenuation</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Europium</topic><topic>Gadolinium</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Luminescence</topic><topic>Optical properties</topic><topic>Phosphors</topic><topic>Photoluminescence</topic><topic>Room temperature</topic><topic>Solid phases</topic><topic>Solid solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Terebilenko, K. V.</creatorcontrib><creatorcontrib>Chornii, V. P.</creatorcontrib><creatorcontrib>Lysenko, A. V.</creatorcontrib><creatorcontrib>Petrenko, O. V.</creatorcontrib><creatorcontrib>Nedilko, S. G.</creatorcontrib><creatorcontrib>Slobodyanik, M. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Theoretical and experimental chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Terebilenko, K. V.</au><au>Chornii, V. P.</au><au>Lysenko, A. V.</au><au>Petrenko, O. V.</au><au>Nedilko, S. G.</au><au>Slobodyanik, M. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of Isostructural Substitution of Gadolinium By Europium(III) on the Luminescent Properties of K3Gd(PO4)2:Eu</atitle><jtitle>Theoretical and experimental chemistry</jtitle><stitle>Theor Exp Chem</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>57</volume><issue>2</issue><spage>121</spage><epage>125</epage><pages>121-125</pages><issn>0040-5760</issn><eissn>1573-935X</eissn><abstract>Solid solutions of K
3
Gd(PO
4
)
2
:Eu containing 0.1 to 10 mole % of europium(III) were obtained by solid-phase interaction. The obtained micropowders were characterized by X-ray phase analysis, IR, and luminescence spectroscopy. It is shown that doping does not affect the symmetry of the double phosphate framework. All studied samples are characterized by intense red photoluminescence at room temperature, which is associated with the
5
D
0
→
7
F
0-4
radiation transitions in Eu
3+
ions. The absence of concentration attenuation and color characteristics of the samples indicate the prospects of using the K
3
Gd
0.9
Eu
0.1
(PO
4
)
2
compound as a red phosphor.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11237-021-09680-8</doi><tpages>5</tpages></addata></record> |
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source | Springer Nature |
subjects | Attenuation Chemistry Chemistry and Materials Science Chemistry/Food Science Europium Gadolinium Infrared analysis Infrared spectroscopy Luminescence Optical properties Phosphors Photoluminescence Room temperature Solid phases Solid solutions |
title | Influence of Isostructural Substitution of Gadolinium By Europium(III) on the Luminescent Properties of K3Gd(PO4)2:Eu |
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