Absolute partial ionization cross sections for electron impact of R-carvone from threshold to 100 eV

Partial ionization cross section (PICS) measurements, of the cations created through electron ionization from threshold to 100 eV, have been taken for 78 cationic fragments of R-carvone, using a HIDEN quadrupole mass spectrometer (EPIC 300) with a mass resolution of 1 amu. These PICSs correspond to...

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Bibliographic Details
Published in:The European physical journal. D, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2021-08, Vol.75 (8), Article 217
Main Authors: Amorim, R. A. A., Pires, W. A. D., Fernandes, A. C. P., Casagrande, T. M., Jones, D. B., Blanco, F., García, G., Brunger, M. J., Lopes, M. C. A.
Format: Article
Language:English
Subjects:
Applications of Nonlinear Dynamics and Chaos Theory
Atomic
Cations
Electron impact
Fragments
Ionization cross sections
Ions
Molecular
Molecular collisions
Optical and Plasma Physics
photoionization and dynamics: honouring Professor Vincent McKoy
Physical Chemistry
Physics
Physics and Astronomy
Quadrupoles
Quantum Information Technology
Quantum Physics
Spectroscopy/Spectrometry
Spintronics
Topical Review - Atomic and Molecular Collisions
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Summary:Partial ionization cross section (PICS) measurements, of the cations created through electron ionization from threshold to 100 eV, have been taken for 78 cationic fragments of R-carvone, using a HIDEN quadrupole mass spectrometer (EPIC 300) with a mass resolution of 1 amu. These PICSs correspond to the cationic fragments with the highest intensity signal registered in our R-carvone mass spectrum reported in Lopes et al. (Int. J. Mass Spectrom. 456, 116395 (2020)) and, to the best of our knowledge, are being presented here for the first time to the scientific community. We also associate the profile observed in the PICSs with some ionic fragmentation mechanisms for R-carvone, based on the appearance energy (AE) values found in Lopes et al. Graphic abstract
ISSN:1434-6060
1434-6079
DOI:10.1140/epjd/s10053-021-00225-1