Solution of the Inverse Chemical Kinetics Problem According to Stationary Multi Experiments

A method for solving the inverse problem of chemical kinetics based on the data of stationary experiments with different initial conditions (multiple experiments), taking into account the measurement errors in an isothermal gradientless reactor, is presented. Examples of using the method for determi...

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Bibliographic Details
Published in:Russian journal of physical chemistry. B 2021-05, Vol.15 (3), p.476-482
Main Author: Koltsov, N. I.
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Experiments
Initial conditions
Inverse problems
Kinetics and Mechanism of Chemical Reactions
Physical Chemistry
Rate constants
Reaction kinetics
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Summary:A method for solving the inverse problem of chemical kinetics based on the data of stationary experiments with different initial conditions (multiple experiments), taking into account the measurement errors in an isothermal gradientless reactor, is presented. Examples of using the method for determining the intervals of the physical values of the rate constants of the stages of multistage nonlinear reactions are given. The influence of the measurement errors on the accuracy and stability of the method is estimated.
ISSN:1990-7931
1990-7923
DOI:10.1134/S1990793121030234