Chemoselective reduction of nitroarenes, N-acetylation of arylamines, and one-pot reductive acetylation of nitroarenes using carbon-supported palladium catalytic system in water

Developing and/or modifying fundamental chemical reactions using chemical industry-favorite heterogeneous recoverable catalytic systems in the water solvent is very important. In this paper, we developed convenient, green, and efficient approaches for the chemoselective reduction of nitroarenes, N -...

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Bibliographic Details
Published in:Research on chemical intermediates 2021-08, Vol.47 (8), p.3289-3312
Main Authors: Zeynizadeh, Behzad, Mohammad Aminzadeh, Farkhondeh, Mousavi, Hossein
Format: Article
Language:English
Subjects:
Acetylation
Amines
Carbon
Catalysis
Chemical industry
Chemical reactions
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Organic compounds
Palladium
Physical Chemistry
Reduction
Solvents
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Summary:Developing and/or modifying fundamental chemical reactions using chemical industry-favorite heterogeneous recoverable catalytic systems in the water solvent is very important. In this paper, we developed convenient, green, and efficient approaches for the chemoselective reduction of nitroarenes, N -acetylation of arylamines, and one-pot reductive acetylation of nitroarenes in the presence of the recoverable heterogeneous carbon-supported palladium (Pd/C) catalytic system in water. The utilize of the simple, effective, and recoverable catalyst and also using of water as an entirely green solvent along with relatively short reaction times and good-to-excellent yields of the desired products are some of the noticeable features of the presented synthetic protocols. Graphic abstract
ISSN:0922-6168
1568-5675
DOI:10.1007/s11164-021-04469-9