Synthesis of polyeugenoxy acetyl thiophene methanolate as a new selective carrier

Research on the Synthesis of Polyeugenoxy Acetyl Thiophene Methanolate (PEATM) as a new selective Carrier using the Bulk Liquid Membrane (BLM) Method has been done. PEATM was synthesized from eugenol that was polymerized to form polyeugenol, acidified to make polieugenoxy acetate and then etherized...

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Bibliographic Details
Published in:IOP conference series. Materials Science and Engineering 2019-05, Vol.509 (1), p.12068
Main Authors: Djunaidi, Muhammad Cholid, Lusiana, Retno Ariadi, Pardoyo, Widodo, Didik Setiyo, Utami, Titi Wulan
Format: Article
Language:English
Subjects:
Acidification
Benzene
Chloroform
Hexanes
Liquid membranes
NMR
Nuclear magnetic resonance
Organic compounds
Polyeugenoxy Acetyl Thiophene Methanolate
selective carrier
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Summary:Research on the Synthesis of Polyeugenoxy Acetyl Thiophene Methanolate (PEATM) as a new selective Carrier using the Bulk Liquid Membrane (BLM) Method has been done. PEATM was synthesized from eugenol that was polymerized to form polyeugenol, acidified to make polieugenoxy acetate and then etherized with thiophenemethanol. The product obtained was characterized using FTIR and 1H-NMR. PEATM produced in the form of thick brownish-black liquid. The solubility test incorporating organic compounds showed that this compound dissolved in chloroform and benzene but was difficult to dissolve in n-hexane. Molecular weight value of 700 was obtained using Ubbollohde viscometer with about 22 times monomer repetition. PEATM was used as a BLM carrier to separate mixture of Cd2+, Cr3+ and Cu2+. The results showed that PEATM was selective towards Cd 2+.
ISSN:1757-8981
1757-899X
1757-899X
DOI:10.1088/1757-899X/509/1/012068