Synthesis of hexenyl aryl tellurides and the catalytic activity of their platinum(II) complexes as polysiloxanesupported catalysts in hydrosilylation of olefins

5-hexenyl 1-naphthyl telluride (1) and 5-hexenyl (1,1'-binaphthyl-2-yl) telluride (2) were prepared from the reaction of 1-bromonaphthalene and 2-bromobinaphthalene with di(5-hexenyl) ditelluride in presence of lithium metal. Reaction of 1 and 2 with K2PtCl4 afforded the platinum(II) complexes...

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Published in:IOP conference series. Materials Science and Engineering 2020-11, Vol.928 (5), p.52031
Main Authors: Al-Rubaie, Ali Z., Al-Khazragie, Zainab K.
Format: Article
Language:English
Subjects:
Alkenes
Catalysts
Catalytic activity
Hexenyl aryl tellurides
Hydrosilylation
Intermetallic compounds
Lithium
Platinum
Platinum (II) complexes
Polysiloxanes
Silica
Silica fume
Silicon dioxide
Supported catalyst
Tellurides
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description 5-hexenyl 1-naphthyl telluride (1) and 5-hexenyl (1,1'-binaphthyl-2-yl) telluride (2) were prepared from the reaction of 1-bromonaphthalene and 2-bromobinaphthalene with di(5-hexenyl) ditelluride in presence of lithium metal. Reaction of 1 and 2 with K2PtCl4 afforded the platinum(II) complexes 3 and 4, respectively in good yields. Silica-bound telluride-platinum complexes were directly synthesized from fumed silica, triethoxysilane and platinum complexes (i.e. 3 and 4). The catalytic activities of polysiloxane-supported platinum complexes were examined with 1-hexene, 1-decene and 1-dodecene at different temperature. It was found that these catalysts are efficient for hydrosilylation of olefins with triethoxysilane.
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subjects Alkenes
Catalysts
Catalytic activity
Hexenyl aryl tellurides
Hydrosilylation
Intermetallic compounds
Lithium
Platinum
Platinum (II) complexes
Polysiloxanes
Silica
Silica fume
Silicon dioxide
Supported catalyst
Tellurides
title Synthesis of hexenyl aryl tellurides and the catalytic activity of their platinum(II) complexes as polysiloxanesupported catalysts in hydrosilylation of olefins
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