Synthesis, LIFDI Mass Spectrometry and Reactivity of Triacyl‐Germenolates

The synthesis of stable triacylgermenolates 3 a,b was achieved by using a multiple silyl ion methodology. The formation of these new germenolates was confirmed by NMR spectroscopy and UV‐Vis measurements. Moreover, for the triacylgermenolates 2 and 3 a LIFDI mass spectrometry to characterize these n...

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Published in:European journal of inorganic chemistry 2021-08, Vol.2021 (30), p.3091-3096
Main Authors: Drusgala, Manfred, Linden, Mathias H., Knoechl, Andreas, Torvisco, Ana, Fischer, Roland C., Bernhard Linden, H., Haas, Michael
Format: Article
Language:English
Subjects:
Absorption spectra
Acylgermanes
Chromophores
Crystallography
Germenolates
Group tolerance
Inorganic chemistry
Ions
Mass spectrometry
NMR spectroscopy
Photoinitiator
Scientific imaging
Spectroscopic analysis
Synthesis
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cited_by cdi_FETCH-LOGICAL-c3571-254cae4c84766240146e1194d8fba14550bcbfe03214bf1a0d894630829579fa3
cites cdi_FETCH-LOGICAL-c3571-254cae4c84766240146e1194d8fba14550bcbfe03214bf1a0d894630829579fa3
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container_issue 30
container_start_page 3091
container_title European journal of inorganic chemistry
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creator Drusgala, Manfred
Linden, Mathias H.
Knoechl, Andreas
Torvisco, Ana
Fischer, Roland C.
Bernhard Linden, H.
Haas, Michael
description The synthesis of stable triacylgermenolates 3 a,b was achieved by using a multiple silyl ion methodology. The formation of these new germenolates was confirmed by NMR spectroscopy and UV‐Vis measurements. Moreover, for the triacylgermenolates 2 and 3 a LIFDI mass spectrometry to characterize these new compounds. Germenolates 3 a,b serve as a starting point for a new triaacylgermane 4 a and two octaacyldigermanes 4 c,d. The formation of these acylgermanes was confirmed by NMR spectroscopy, X‐ray crystallography, UV‐Vis measurements and mass spectrometry. The UV‐Vis absorption spectra of 4 c,d show considerably increased band intensities due to the presence of eight chromophores. New Germenolates. A multiple silyl ion pathway was used to isolate two new germenolates. Their formation was confirmed by NMR spectroscopy, UV−Vis measurements as well as LIFDI mass spectrometry was used to exclude any radical side products. These germenolates serve as a starting point for new acylgermanes.
doi_str_mv 10.1002/ejic.202100441
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subjects Absorption spectra
Acylgermanes
Chromophores
Crystallography
Germenolates
Group tolerance
Inorganic chemistry
Ions
Mass spectrometry
NMR spectroscopy
Photoinitiator
Scientific imaging
Spectroscopic analysis
Synthesis
title Synthesis, LIFDI Mass Spectrometry and Reactivity of Triacyl‐Germenolates
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