Recent advances in synthesis and crystal structures of metal pentazolate salts

Pentazole is the last member of the azole family. As a five-membered ring constructed from nitrogen, a pentazole skeleton is a good nitrogen-donor ligand, which possesses great potential to prepare intriguing multidimensional structures. In recent years, a series of metal pentazolate salts have been...

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Bibliographic Details
Published in:CrystEngComm 2021-09, Vol.23 (33), p.5551-5559
Main Authors: Xia, Honglei, Zhang, Wenquan, Cao, Yuteng, Zhang, Qinghua
Format: Article
Language:English
Subjects:
Crystal structure
Crystals
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Summary:Pentazole is the last member of the azole family. As a five-membered ring constructed from nitrogen, a pentazole skeleton is a good nitrogen-donor ligand, which possesses great potential to prepare intriguing multidimensional structures. In recent years, a series of metal pentazolate salts have been synthesized, which have attracted immense attention due to their interesting crystal structures. In this study, an overview of all the reported metal pentazolate salts is provided; furthermore, the key issues to be solved and future prospects in this field are also discussed. Pentazole is a good nitrogen-donor ligand to prepare intriguing structures. Herein, the synthesis and crystal structures of all reported metal pentazolate salts were summarized and the future prospects in this field were also discussed.
ISSN:1466-8033
1466-8033
DOI:10.1039/d1ce00635e