Conformer of the peroxynitrite ion formed under photolysis of crystalline alkali nitrates - cis or trans?

The optical and infrared reflectance spectra of the crystalline powders prepared by co-crystallization of caesium nitrate, nitrite, and peroxynitrite from alkali solution have been studied. We find that the trans conformer forms under photolysis of crystalline pure caesium nitrate. Under its dissolu...

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Bibliographic Details
Published in:IOP conference series. Materials Science and Engineering 2017-01, Vol.168 (1), p.12091
Main Authors: Pak, V Kh, Anan'ev, V A, Dyagileva, E P, Lyrshchikov, S Yu, Miklin, M B, Rezvova, M A
Format: Article
Language:English
Subjects:
Cesium
Cocrystallization
Crystal structure
Crystallinity
Crystallization
Infrared reflection
Infrared spectra
Photolysis
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Summary:The optical and infrared reflectance spectra of the crystalline powders prepared by co-crystallization of caesium nitrate, nitrite, and peroxynitrite from alkali solution have been studied. We find that the trans conformer forms under photolysis of crystalline pure caesium nitrate. Under its dissolution the trans conformer transforms to the cis conformer.
ISSN:1757-8981
1757-899X
DOI:10.1088/1757-899X/168/1/012091