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Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)

The electron paramagnetic spectra of trigonal Mn 2+ centers in [Co(H 2 O) 6 ]SiF 6 , [Co(H 2 O) 6 ] SnF 6 , and [Co(H 2 O) 6 ]PtCl 6 crystals were studied on the basis of the complete energy matrices for a d 5 configuration ion in a trigonal ligand field. When Mn 2+ is doped in the [Co(H 2 O) 6 ]SiF...

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Published in:Journal of Wuhan University of Technology. Materials science edition 2021-08, Vol.36 (4), p.595-599
Main Authors: Li, Jufen, Su, Juan, Yi, Xuebin, Tang, Bin, Wu, Xinhui, Zhong, Shuirong
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container_title Journal of Wuhan University of Technology. Materials science edition
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Su, Juan
Yi, Xuebin
Tang, Bin
Wu, Xinhui
Zhong, Shuirong
description The electron paramagnetic spectra of trigonal Mn 2+ centers in [Co(H 2 O) 6 ]SiF 6 , [Co(H 2 O) 6 ] SnF 6 , and [Co(H 2 O) 6 ]PtCl 6 crystals were studied on the basis of the complete energy matrices for a d 5 configuration ion in a trigonal ligand field. When Mn 2+ is doped in the [Co(H 2 O) 6 ]SiF 6 , [Co(H 2 O) 6 ]SnF 6 , and [Co(H 2 O) 6 ]PtCl 6 crystals crystals, there is a similar local distortion. The experimental results show that the local lattice structure around a trigonal Mn 2+ center has an elongation distortion along the crystalline C 3 axis. From the EPR calculation, the local lattice structure parameters R =2.278A, θ =52.6406° for [Co(H 2 O) 6 ]SiF 6 , R =2.280, θ =52.4936° for [Co(H 2 O) 6 ]SnF 6 and R =2.244A, θ =53.0616° for [Co(H 2 O) 6 ]PtCl 6 were determined.
doi_str_mv 10.1007/s11595-021-2449-z
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When Mn 2+ is doped in the [Co(H 2 O) 6 ]SiF 6 , [Co(H 2 O) 6 ]SnF 6 , and [Co(H 2 O) 6 ]PtCl 6 crystals crystals, there is a similar local distortion. The experimental results show that the local lattice structure around a trigonal Mn 2+ center has an elongation distortion along the crystalline C 3 axis. From the EPR calculation, the local lattice structure parameters R =2.278A, θ =52.6406° for [Co(H 2 O) 6 ]SiF 6 , R =2.280, θ =52.4936° for [Co(H 2 O) 6 ]SnF 6 and R =2.244A, θ =53.0616° for [Co(H 2 O) 6 ]PtCl 6 were determined.</description><identifier>ISSN: 1000-2413</identifier><identifier>EISSN: 1993-0437</identifier><identifier>DOI: 10.1007/s11595-021-2449-z</identifier><language>eng</language><publisher>Wuhan: Wuhan University of Technology</publisher><subject>Chemistry and Materials Science ; Crystals ; Distortion ; Elongated structure ; Manganese ions ; Materials Science ; Metallic Materials</subject><ispartof>Journal of Wuhan University of Technology. 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From the EPR calculation, the local lattice structure parameters R =2.278A, θ =52.6406° for [Co(H 2 O) 6 ]SiF 6 , R =2.280, θ =52.4936° for [Co(H 2 O) 6 ]SnF 6 and R =2.244A, θ =53.0616° for [Co(H 2 O) 6 ]PtCl 6 were determined.</abstract><cop>Wuhan</cop><pub>Wuhan University of Technology</pub><doi>10.1007/s11595-021-2449-z</doi><tpages>5</tpages></addata></record>
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1993-0437
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subjects Chemistry and Materials Science
Crystals
Distortion
Elongated structure
Manganese ions
Materials Science
Metallic Materials
title Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)
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