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Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)
The electron paramagnetic spectra of trigonal Mn 2+ centers in [Co(H 2 O) 6 ]SiF 6 , [Co(H 2 O) 6 ] SnF 6 , and [Co(H 2 O) 6 ]PtCl 6 crystals were studied on the basis of the complete energy matrices for a d 5 configuration ion in a trigonal ligand field. When Mn 2+ is doped in the [Co(H 2 O) 6 ]SiF...
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Published in: | Journal of Wuhan University of Technology. Materials science edition 2021-08, Vol.36 (4), p.595-599 |
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creator | Li, Jufen Su, Juan Yi, Xuebin Tang, Bin Wu, Xinhui Zhong, Shuirong |
description | The electron paramagnetic spectra of trigonal Mn
2+
centers in [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
] SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals were studied on the basis of the complete energy matrices for a d
5
configuration ion in a trigonal ligand field. When Mn
2+
is doped in the [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
]SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals crystals, there is a similar local distortion. The experimental results show that the local lattice structure around a trigonal Mn
2+
center has an elongation distortion along the crystalline C
3
axis. From the EPR calculation, the local lattice structure parameters
R
=2.278A,
θ
=52.6406° for [Co(H
2
O)
6
]SiF
6
,
R
=2.280,
θ
=52.4936° for [Co(H
2
O)
6
]SnF
6
and
R
=2.244A,
θ
=53.0616° for [Co(H
2
O)
6
]PtCl
6
were determined. |
doi_str_mv | 10.1007/s11595-021-2449-z |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2566054324</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2566054324</sourcerecordid><originalsourceid>FETCH-LOGICAL-c198t-c638542c10cdf11bd29af2217771323b254eaf68dcd1e707d93d6f4c2d7dd46c3</originalsourceid><addsrcrecordid>eNp1kMtKw0AUhgdRsFYfwN2AmxY7OrdMGqSLEuwFlApVaBUZ0rmUlJipM-mifXpTIrhydQ6c7__hfABcE3xHMI7vAyFREiFMCaKcJ-hwAlokSRjCnMWn9Y4xri-EnYOLEDYYc8yEaAE1LLNiH_IAnYVj73alRqHKKgPfjXfI5qbQcL4t8qrKyzW0zsPnkt7CqSsDzEv4kbrOhM66n4ulgJ3FYJ734LzswZfqAS4Hox5Mi-4lOLNZEczV72yDt9HjazpBT7PxNB0-IUWSfoWUYP2IU0Ww0paQlaZJZiklcRwTRtmKRtxkVvS10sTEONYJ08JyRXWsNReKtcFN07v17ntnQiU3bufr_4KkkRA44ozymiINpbwLwRsrtz7_yvxeEiyPLmXjUtYu5dGlPNQZ2mRCzZZr4_-a_w_9ABwkcy4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2566054324</pqid></control><display><type>article</type><title>Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)</title><source>Springer Link</source><creator>Li, Jufen ; Su, Juan ; Yi, Xuebin ; Tang, Bin ; Wu, Xinhui ; Zhong, Shuirong</creator><creatorcontrib>Li, Jufen ; Su, Juan ; Yi, Xuebin ; Tang, Bin ; Wu, Xinhui ; Zhong, Shuirong</creatorcontrib><description>The electron paramagnetic spectra of trigonal Mn
2+
centers in [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
] SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals were studied on the basis of the complete energy matrices for a d
5
configuration ion in a trigonal ligand field. When Mn
2+
is doped in the [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
]SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals crystals, there is a similar local distortion. The experimental results show that the local lattice structure around a trigonal Mn
2+
center has an elongation distortion along the crystalline C
3
axis. From the EPR calculation, the local lattice structure parameters
R
=2.278A,
θ
=52.6406° for [Co(H
2
O)
6
]SiF
6
,
R
=2.280,
θ
=52.4936° for [Co(H
2
O)
6
]SnF
6
and
R
=2.244A,
θ
=53.0616° for [Co(H
2
O)
6
]PtCl
6
were determined.</description><identifier>ISSN: 1000-2413</identifier><identifier>EISSN: 1993-0437</identifier><identifier>DOI: 10.1007/s11595-021-2449-z</identifier><language>eng</language><publisher>Wuhan: Wuhan University of Technology</publisher><subject>Chemistry and Materials Science ; Crystals ; Distortion ; Elongated structure ; Manganese ions ; Materials Science ; Metallic Materials</subject><ispartof>Journal of Wuhan University of Technology. Materials science edition, 2021-08, Vol.36 (4), p.595-599</ispartof><rights>Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature 2021</rights><rights>Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-c638542c10cdf11bd29af2217771323b254eaf68dcd1e707d93d6f4c2d7dd46c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Jufen</creatorcontrib><creatorcontrib>Su, Juan</creatorcontrib><creatorcontrib>Yi, Xuebin</creatorcontrib><creatorcontrib>Tang, Bin</creatorcontrib><creatorcontrib>Wu, Xinhui</creatorcontrib><creatorcontrib>Zhong, Shuirong</creatorcontrib><title>Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)</title><title>Journal of Wuhan University of Technology. Materials science edition</title><addtitle>J. Wuhan Univ. Technol.-Mat. Sci. Edit</addtitle><description>The electron paramagnetic spectra of trigonal Mn
2+
centers in [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
] SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals were studied on the basis of the complete energy matrices for a d
5
configuration ion in a trigonal ligand field. When Mn
2+
is doped in the [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
]SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals crystals, there is a similar local distortion. The experimental results show that the local lattice structure around a trigonal Mn
2+
center has an elongation distortion along the crystalline C
3
axis. From the EPR calculation, the local lattice structure parameters
R
=2.278A,
θ
=52.6406° for [Co(H
2
O)
6
]SiF
6
,
R
=2.280,
θ
=52.4936° for [Co(H
2
O)
6
]SnF
6
and
R
=2.244A,
θ
=53.0616° for [Co(H
2
O)
6
]PtCl
6
were determined.</description><subject>Chemistry and Materials Science</subject><subject>Crystals</subject><subject>Distortion</subject><subject>Elongated structure</subject><subject>Manganese ions</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><issn>1000-2413</issn><issn>1993-0437</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKw0AUhgdRsFYfwN2AmxY7OrdMGqSLEuwFlApVaBUZ0rmUlJipM-mifXpTIrhydQ6c7__hfABcE3xHMI7vAyFREiFMCaKcJ-hwAlokSRjCnMWn9Y4xri-EnYOLEDYYc8yEaAE1LLNiH_IAnYVj73alRqHKKgPfjXfI5qbQcL4t8qrKyzW0zsPnkt7CqSsDzEv4kbrOhM66n4ulgJ3FYJ734LzswZfqAS4Hox5Mi-4lOLNZEczV72yDt9HjazpBT7PxNB0-IUWSfoWUYP2IU0Ww0paQlaZJZiklcRwTRtmKRtxkVvS10sTEONYJ08JyRXWsNReKtcFN07v17ntnQiU3bufr_4KkkRA44ozymiINpbwLwRsrtz7_yvxeEiyPLmXjUtYu5dGlPNQZ2mRCzZZr4_-a_w_9ABwkcy4</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Li, Jufen</creator><creator>Su, Juan</creator><creator>Yi, Xuebin</creator><creator>Tang, Bin</creator><creator>Wu, Xinhui</creator><creator>Zhong, Shuirong</creator><general>Wuhan University of Technology</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20210801</creationdate><title>Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)</title><author>Li, Jufen ; Su, Juan ; Yi, Xuebin ; Tang, Bin ; Wu, Xinhui ; Zhong, Shuirong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-c638542c10cdf11bd29af2217771323b254eaf68dcd1e707d93d6f4c2d7dd46c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry and Materials Science</topic><topic>Crystals</topic><topic>Distortion</topic><topic>Elongated structure</topic><topic>Manganese ions</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Jufen</creatorcontrib><creatorcontrib>Su, Juan</creatorcontrib><creatorcontrib>Yi, Xuebin</creatorcontrib><creatorcontrib>Tang, Bin</creatorcontrib><creatorcontrib>Wu, Xinhui</creatorcontrib><creatorcontrib>Zhong, Shuirong</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of Wuhan University of Technology. Materials science edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Jufen</au><au>Su, Juan</au><au>Yi, Xuebin</au><au>Tang, Bin</au><au>Wu, Xinhui</au><au>Zhong, Shuirong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl)</atitle><jtitle>Journal of Wuhan University of Technology. Materials science edition</jtitle><stitle>J. Wuhan Univ. Technol.-Mat. Sci. Edit</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>36</volume><issue>4</issue><spage>595</spage><epage>599</epage><pages>595-599</pages><issn>1000-2413</issn><eissn>1993-0437</eissn><abstract>The electron paramagnetic spectra of trigonal Mn
2+
centers in [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
] SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals were studied on the basis of the complete energy matrices for a d
5
configuration ion in a trigonal ligand field. When Mn
2+
is doped in the [Co(H
2
O)
6
]SiF
6
, [Co(H
2
O)
6
]SnF
6
, and [Co(H
2
O)
6
]PtCl
6
crystals crystals, there is a similar local distortion. The experimental results show that the local lattice structure around a trigonal Mn
2+
center has an elongation distortion along the crystalline C
3
axis. From the EPR calculation, the local lattice structure parameters
R
=2.278A,
θ
=52.6406° for [Co(H
2
O)
6
]SiF
6
,
R
=2.280,
θ
=52.4936° for [Co(H
2
O)
6
]SnF
6
and
R
=2.244A,
θ
=53.0616° for [Co(H
2
O)
6
]PtCl
6
were determined.</abstract><cop>Wuhan</cop><pub>Wuhan University of Technology</pub><doi>10.1007/s11595-021-2449-z</doi><tpages>5</tpages></addata></record> |
fulltext | fulltext |
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ispartof | Journal of Wuhan University of Technology. Materials science edition, 2021-08, Vol.36 (4), p.595-599 |
issn | 1000-2413 1993-0437 |
language | eng |
recordid | cdi_proquest_journals_2566054324 |
source | Springer Link |
subjects | Chemistry and Materials Science Crystals Distortion Elongated structure Manganese ions Materials Science Metallic Materials |
title | Analysis of Ground-state Zero-field Splitting for Mn2+ Ions in [Co(H2O)]XY6 (X=Si, Sn, Pt; Y=F, Cl) |
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