Sodium Sulfide in the Synthesis of N-Alkyl-1,3,5-dithiazinanes and 1,3,5-Thiadiazinanes

An approach to the synthesis of 1,3,5-dithiazinanes and 1,3,5-thiadiazinanes was developed based on the cyclothiomethylation of aliphatic amines with 9-aqueous Na 2 S and CH 2 O. Linear aliphatic primary amines form predominantly 1,3,5-thiadiazinanes, while branched ones lead to the formation of 1,3...

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Bibliographic Details
Published in:Russian journal of general chemistry 2021-08, Vol.91 (8), p.1453-1458
Main Authors: Khabibullina, G. R., Yapparova, D. K., Ibragimov, A. G., Akhmetova, V. R.
Format: Article
Language:English
Subjects:
Aliphatic amines
Amines
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Sodium sulfide
Sulfides
Synthesis
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Summary:An approach to the synthesis of 1,3,5-dithiazinanes and 1,3,5-thiadiazinanes was developed based on the cyclothiomethylation of aliphatic amines with 9-aqueous Na 2 S and CH 2 O. Linear aliphatic primary amines form predominantly 1,3,5-thiadiazinanes, while branched ones lead to the formation of 1,3,5-dithiazinanes.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363221080053