Amidophenolate Tantalum Complexes

Mixed-ligand amidophenolate complexes [Ta(AP Dipp )(NMe 2 ) 3 ] ( I ) and [Ta(AP Dipp ) 2 (NMe 2 )] ( II ) were obtained by the reaction of Ta(NMe 2 ) 5 with 2,4-di- tert -butyl-6-((2,6-diisopropylphenyl)amino)phenol (H 2 AP Dipp ). The products were characterized by X-ray diffraction (CIF file CCDC...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2021-09, Vol.47 (9), p.587-592
Main Authors: Petrov, P. A., Golubitskaya, E. A., El’tsov, I. V., Sukhikh, T. S., Sokolov, M. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination compounds
Inorganic Chemistry
NMR spectroscopy
Physical Chemistry
Tantalum
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Summary:Mixed-ligand amidophenolate complexes [Ta(AP Dipp )(NMe 2 ) 3 ] ( I ) and [Ta(AP Dipp ) 2 (NMe 2 )] ( II ) were obtained by the reaction of Ta(NMe 2 ) 5 with 2,4-di- tert -butyl-6-((2,6-diisopropylphenyl)amino)phenol (H 2 AP Dipp ). The products were characterized by X-ray diffraction (CIF file CCDC nos. 2060699 ( I ), 2060700 ( II ∙0.5C 5 H 12 )) and NMR spectroscopy.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328421090074