The Influence of Acetic Acid on the Properties of Microporous Metal–organic Framework MIL-88a at Microfluidic Conditions and room Temperature

This paper presents a new eco-friendly technique for the microfluidic synthesis of metal–organic framework MIL-88a in an aqueous medium at room temperature. Acetic acid as a modulator was used to control the morphology and size of the resulting particles during the synthesis. An increase of acetic a...

Full description

Saved in:
Bibliographic Details
Published in:Nanobiotechnology Reports (Online) 2021-07, Vol.16 (4), p.488-496
Main Authors: Medvedev, P. V., Butova, V. V., Soldatov, M. A., Kuzharov, A. A., Fedorenko, A. G., Shapovalova (Cherkasova), S. O., Burachevskaya, O. A., Gorban, I. E., Soldatov, A. V.
Format: Article
Language:English
Subjects:
Acetic acid
Aqueous solutions
Chemistry and Materials Science
Fourier transforms
Functional and Construction Nanomaterials
Industrial and Production Engineering
Low temperature
Machines
Manufacturing
Materials Science
Metal-organic frameworks
Microfluidics
Morphology
Nanotechnology
Porosity
Processes
Room temperature
Synthesis
Thermogravimetry
X ray powder diffraction
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:This paper presents a new eco-friendly technique for the microfluidic synthesis of metal–organic framework MIL-88a in an aqueous medium at room temperature. Acetic acid as a modulator was used to control the morphology and size of the resulting particles during the synthesis. An increase of acetic acid concentration in a certain range of molar ratios leads to a decrease in the linear size of obtained particles and makes it possible to obtain a material with monodisperse porosity. The synthesized samples were comprehensively characterized by powder X-ray diffraction, Fourier-transform infrared spectroscopy, thermogravimetry, and transmission electron microscopy. The porosity of the obtained materials was calculated according to the BET model, based on the data of low-temperature nitrogen adsorption.
ISSN:2635-1676
1995-0780
2635-1684
1995-0799
DOI:10.1134/S2635167621040066