Evaluation of Calcium Alginate-Based Biopolymers as Potential Component of Membranes for Recovering Biosurfactants from Corn Steep Water

Corn steep water (CSW) is a complex agro-food stream that is used as a source of cost-competitive biosurfactants, since they are produced spontaneously in the steeping process of corn, avoiding production costs. Nevertheless, the extraction of biosurfactants from CSW using sustainable processes is s...

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Bibliographic Details
Published in:Water (Basel) 2021-09, Vol.13 (17), p.2396
Main Authors: Martínez-Arcos, Andrea, Reig, Mònica, Cruz, José Manuel, Cortina, José Luis, Moldes, Ana Belén, Vecino, Xanel
Format: Article
Language:English
Subjects:
Adsorption
Alginic acid
Anions
Biodegradation
Biomolecules
Biopolymers
Biosurfactants
Calcium
Calcium alginate
Calcium compounds
Carbohydrates
Carbon
Cations
Corn
Crop production
Experiments
Grapes
Mass spectrometry
Membranes
Metals
Microorganisms
Organic acids
Polymers
Production costs
Recovering
Scientific imaging
Sodium
Solutes
Solvents
Streams
Sugar
Surfactants
Vegetables
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Summary:Corn steep water (CSW) is a complex agro-food stream that is used as a source of cost-competitive biosurfactants, since they are produced spontaneously in the steeping process of corn, avoiding production costs. Nevertheless, the extraction of biosurfactants from CSW using sustainable processes is still a challenge. Consequently, the use of calcium alginate membranes could present a novel and sustainable technology for recovering biosurfactants from aqueous streams. Therefore, the aim of this work is to evaluate calcium alginate-based biopolymers, without and with the presence of grape marc as an additive, as a key component of membranes for the recovery of biosurfactants in corn steep water. Biosurfactants are present in CSW, together with other inorganic solutes and biomolecules, such as organic acids, sugars, cations, anions as well as metals. Hence, the competition of these mentioned compounds for the active sites of the calcium alginate-based biopolymers was high. However, they showed a good adsorption capacity for biosurfactants, recovering around 55 ± 2% and 47 ± 1%, of biosurfactants from CSW using both calcium alginate-based biopolymers, with and without biodegraded grape marc. Regarding adsorption capacity, it was 54.8 ± 0.6 mg biosurfactant/g bioadsorbent for the biopolymer containing grape marc, and 46.8 ± 0.4 mg biosurfactant/g bioadsorbent for the calcium alginate-based biopolymer alone. Based on these results, it could be postulated that the formulation of green membranes, based on calcium alginate-based polymers, could be an interesting alternative for the recovery of biosurfactants from aqueous streams including CSW.
ISSN:2073-4441
2073-4441
DOI:10.3390/w13172396