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MOF-derived Co3O4@rGO nanocomposites as anodes for high-performance lithium-ion batteries

The Co 3 O 4 @rGO derived from metal–organic frameworks (MOFs) were prepared by a simple solvothermal method followed by the heat treatment. In a typical preparation process, the Co-MOF (ZIF-67) acts as the precursor to obtain desirable nano Co 3 O 4 while the reduced graphene oxide (rGO) layer enha...

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Published in:Ionics 2021-10, Vol.27 (10), p.4197-4204
Main Authors: Wang, Fengyue, Ye, Yusheng, Wang, Zhimeng, Lu, Jiahao, Zhang, Qi, Zhou, Xinping, Xiong, Qiming, Qiu, Xiangyun, Wei, Tao
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cites cdi_FETCH-LOGICAL-c319t-42032b4c1c92102296153386a52c5249efcd2448145d437289f42eba063db7123
container_end_page 4204
container_issue 10
container_start_page 4197
container_title Ionics
container_volume 27
creator Wang, Fengyue
Ye, Yusheng
Wang, Zhimeng
Lu, Jiahao
Zhang, Qi
Zhou, Xinping
Xiong, Qiming
Qiu, Xiangyun
Wei, Tao
description The Co 3 O 4 @rGO derived from metal–organic frameworks (MOFs) were prepared by a simple solvothermal method followed by the heat treatment. In a typical preparation process, the Co-MOF (ZIF-67) acts as the precursor to obtain desirable nano Co 3 O 4 while the reduced graphene oxide (rGO) layer enhances the conductivity. The materials were respectively characterized by XRD, SEM, and then further electrochemical tests. As anode materials for lithium-ion batteries (LIBs), the material of Co 3 O 4 @rGO exhibit overall superb electrochemical properties especially when the rGO proportion is 20%, it displays higher capacity (818.5 mAh g −1 at 100 mA g −1 ), higher cycling stability (87.3% capacity retention after 100 cycles), and better rate performance. The work may throw some lights on the preparation of other transition metal oxides by structure design with rGO layer for further applications. Graphical abstract
doi_str_mv 10.1007/s11581-021-04225-4
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In a typical preparation process, the Co-MOF (ZIF-67) acts as the precursor to obtain desirable nano Co 3 O 4 while the reduced graphene oxide (rGO) layer enhances the conductivity. The materials were respectively characterized by XRD, SEM, and then further electrochemical tests. As anode materials for lithium-ion batteries (LIBs), the material of Co 3 O 4 @rGO exhibit overall superb electrochemical properties especially when the rGO proportion is 20%, it displays higher capacity (818.5 mAh g −1 at 100 mA g −1 ), higher cycling stability (87.3% capacity retention after 100 cycles), and better rate performance. The work may throw some lights on the preparation of other transition metal oxides by structure design with rGO layer for further applications. 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subjects Anodes
Chemistry
Chemistry and Materials Science
Cobalt oxides
Condensed Matter Physics
Electrochemical analysis
Electrochemistry
Electrode materials
Energy Storage
Graphene
Heat treatment
Lithium
Lithium-ion batteries
Metal-organic frameworks
Nanocomposites
Optical and Electronic Materials
Original Paper
Rechargeable batteries
Renewable and Green Energy
Transition metal oxides
title MOF-derived Co3O4@rGO nanocomposites as anodes for high-performance lithium-ion batteries
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