Loading…
Dysphania ambrosioides Essential Oil: An Eco-friendly Inhibitor for Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Medium
The medicinal plant products have been found to be active and eco-friendly anticorrosion agents. Corrosion inhibition of essential oil of Dysphania ambrosioides ( DAEO ) were investigated on mild steel C38 in 0.5 M H 2 SO 4 and 1 M HCl solutions at different concentrations effect and different tempe...
Saved in:
| Published in: | Journal of bio- and tribo-corrosion 2021-12, Vol.7 (4), Article 150 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3 |
| container_end_page | |
| container_issue | 4 |
| container_start_page | |
| container_title | Journal of bio- and tribo-corrosion |
| container_volume | 7 |
| creator | Mirinioui, Amine El Attari, Hassan Fdil, Rabiaa Zefzoufi, Manal Jorio, Souad |
| description | The medicinal plant products have been found to be active and eco-friendly anticorrosion agents. Corrosion inhibition of essential oil of
Dysphania ambrosioides
(
DAEO
) were investigated on mild steel C38 in 0.5 M H
2
SO
4
and 1 M HCl solutions at different concentrations effect and different temperatures was evaluated using the weight-loss method and electrochemical measurements. The results indicated a maximum inhibition efficiency of 90% in 1 M HCl and 91% in 0.5 M H
2
SO
4
which was reached using 4 g/L of
DAEO
at 298 K. The results obtained by electrochemical impedance spectroscopy show that the inhibitory action of this extract is based on the increase of the charge transfer resistance and the decrease of the double layer capacity. In addition, thermodynamic parameters, such as standard enthalpy of adsorption (Δ
H°
ads
), standard free energy adsorption rate (Δ
G°
ads
), and standard entropy of adsorption (Δ
S°
ads
) were used to elucidate
DAEO
inhibitory action. In particular, density-functional theory (DFT) based methods, very suitable to study the electronic structure of mild steel and the main
DAEO
products. The quantum chemical parameters were measured and discussed. |
| doi_str_mv | 10.1007/s40735-021-00584-7 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2575849180</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2575849180</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3</originalsourceid><addsrcrecordid>eNp9kMFPwyAUxonRxGXuH_BE4hkFWkbrbZnTLdmyg3omFKhj6WBCe-jR_1y2Gr15eDxe8n3fgx8AtwTfE4z5Q8wxzxjClCCMWZEjfgFGlJQFymlWXv7eKb4Gkxj3GGPKs5xndAS-nvp43ElnJZSHKvhovdUmwkWMxrVWNnBrm0c4c3ChPKqDNU43PVy5na1s6wOsU21so-Fra0wD5z6cQxy0Di57HbzaNT5YBaVLmq6pu9MwU1bDjdG2O9yAq1o20Ux--hi8Py_e5ku03r6s5rM1UjS9FU1JrSudk0ISygxjhEgttZKMK5mVnGjNdRqKaZZOUhUEm2muWcFkyTnO62wM7obcY_CfnYmt2PsuuLRSUMYTtpIUOKnooFLpGzGYWhyDPcjQC4LFibYYaItEW5xpC55M2WCKSew-TPiL_sf1DbWRgr8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2575849180</pqid></control><display><type>article</type><title>Dysphania ambrosioides Essential Oil: An Eco-friendly Inhibitor for Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Medium</title><source>Springer Nature</source><creator>Mirinioui, Amine ; El Attari, Hassan ; Fdil, Rabiaa ; Zefzoufi, Manal ; Jorio, Souad</creator><creatorcontrib>Mirinioui, Amine ; El Attari, Hassan ; Fdil, Rabiaa ; Zefzoufi, Manal ; Jorio, Souad</creatorcontrib><description>The medicinal plant products have been found to be active and eco-friendly anticorrosion agents. Corrosion inhibition of essential oil of
Dysphania ambrosioides
(
DAEO
) were investigated on mild steel C38 in 0.5 M H
2
SO
4
and 1 M HCl solutions at different concentrations effect and different temperatures was evaluated using the weight-loss method and electrochemical measurements. The results indicated a maximum inhibition efficiency of 90% in 1 M HCl and 91% in 0.5 M H
2
SO
4
which was reached using 4 g/L of
DAEO
at 298 K. The results obtained by electrochemical impedance spectroscopy show that the inhibitory action of this extract is based on the increase of the charge transfer resistance and the decrease of the double layer capacity. In addition, thermodynamic parameters, such as standard enthalpy of adsorption (Δ
H°
ads
), standard free energy adsorption rate (Δ
G°
ads
), and standard entropy of adsorption (Δ
S°
ads
) were used to elucidate
DAEO
inhibitory action. In particular, density-functional theory (DFT) based methods, very suitable to study the electronic structure of mild steel and the main
DAEO
products. The quantum chemical parameters were measured and discussed.</description><identifier>ISSN: 2198-4220</identifier><identifier>EISSN: 2198-4239</identifier><identifier>DOI: 10.1007/s40735-021-00584-7</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Adsorption ; Biomaterials ; Charge transfer ; Chemistry and Materials Science ; Corrosion ; Corrosion and Coatings ; Corrosion inhibitors ; Corrosion prevention ; Corrosion products ; Density functional theory ; Dysphania ambrosioides ; Electrochemical impedance spectroscopy ; Electronic structure ; Enthalpy ; Entropy ; Essential oils ; Free energy ; Herbal medicine ; Low carbon steels ; Materials Science ; Medicinal plants ; Oils & fats ; Parameters ; Quantum chemistry ; Solid Mechanics ; Spectroscopy ; Steel ; Sulfuric acid ; Tribology</subject><ispartof>Journal of bio- and tribo-corrosion, 2021-12, Vol.7 (4), Article 150</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3</citedby><cites>FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Mirinioui, Amine</creatorcontrib><creatorcontrib>El Attari, Hassan</creatorcontrib><creatorcontrib>Fdil, Rabiaa</creatorcontrib><creatorcontrib>Zefzoufi, Manal</creatorcontrib><creatorcontrib>Jorio, Souad</creatorcontrib><title>Dysphania ambrosioides Essential Oil: An Eco-friendly Inhibitor for Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Medium</title><title>Journal of bio- and tribo-corrosion</title><addtitle>J Bio Tribo Corros</addtitle><description>The medicinal plant products have been found to be active and eco-friendly anticorrosion agents. Corrosion inhibition of essential oil of
Dysphania ambrosioides
(
DAEO
) were investigated on mild steel C38 in 0.5 M H
2
SO
4
and 1 M HCl solutions at different concentrations effect and different temperatures was evaluated using the weight-loss method and electrochemical measurements. The results indicated a maximum inhibition efficiency of 90% in 1 M HCl and 91% in 0.5 M H
2
SO
4
which was reached using 4 g/L of
DAEO
at 298 K. The results obtained by electrochemical impedance spectroscopy show that the inhibitory action of this extract is based on the increase of the charge transfer resistance and the decrease of the double layer capacity. In addition, thermodynamic parameters, such as standard enthalpy of adsorption (Δ
H°
ads
), standard free energy adsorption rate (Δ
G°
ads
), and standard entropy of adsorption (Δ
S°
ads
) were used to elucidate
DAEO
inhibitory action. In particular, density-functional theory (DFT) based methods, very suitable to study the electronic structure of mild steel and the main
DAEO
products. The quantum chemical parameters were measured and discussed.</description><subject>Adsorption</subject><subject>Biomaterials</subject><subject>Charge transfer</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion</subject><subject>Corrosion and Coatings</subject><subject>Corrosion inhibitors</subject><subject>Corrosion prevention</subject><subject>Corrosion products</subject><subject>Density functional theory</subject><subject>Dysphania ambrosioides</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electronic structure</subject><subject>Enthalpy</subject><subject>Entropy</subject><subject>Essential oils</subject><subject>Free energy</subject><subject>Herbal medicine</subject><subject>Low carbon steels</subject><subject>Materials Science</subject><subject>Medicinal plants</subject><subject>Oils & fats</subject><subject>Parameters</subject><subject>Quantum chemistry</subject><subject>Solid Mechanics</subject><subject>Spectroscopy</subject><subject>Steel</subject><subject>Sulfuric acid</subject><subject>Tribology</subject><issn>2198-4220</issn><issn>2198-4239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kMFPwyAUxonRxGXuH_BE4hkFWkbrbZnTLdmyg3omFKhj6WBCe-jR_1y2Gr15eDxe8n3fgx8AtwTfE4z5Q8wxzxjClCCMWZEjfgFGlJQFymlWXv7eKb4Gkxj3GGPKs5xndAS-nvp43ElnJZSHKvhovdUmwkWMxrVWNnBrm0c4c3ChPKqDNU43PVy5na1s6wOsU21so-Fra0wD5z6cQxy0Di57HbzaNT5YBaVLmq6pu9MwU1bDjdG2O9yAq1o20Ux--hi8Py_e5ku03r6s5rM1UjS9FU1JrSudk0ISygxjhEgttZKMK5mVnGjNdRqKaZZOUhUEm2muWcFkyTnO62wM7obcY_CfnYmt2PsuuLRSUMYTtpIUOKnooFLpGzGYWhyDPcjQC4LFibYYaItEW5xpC55M2WCKSew-TPiL_sf1DbWRgr8</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Mirinioui, Amine</creator><creator>El Attari, Hassan</creator><creator>Fdil, Rabiaa</creator><creator>Zefzoufi, Manal</creator><creator>Jorio, Souad</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211201</creationdate><title>Dysphania ambrosioides Essential Oil: An Eco-friendly Inhibitor for Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Medium</title><author>Mirinioui, Amine ; El Attari, Hassan ; Fdil, Rabiaa ; Zefzoufi, Manal ; Jorio, Souad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Biomaterials</topic><topic>Charge transfer</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion</topic><topic>Corrosion and Coatings</topic><topic>Corrosion inhibitors</topic><topic>Corrosion prevention</topic><topic>Corrosion products</topic><topic>Density functional theory</topic><topic>Dysphania ambrosioides</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electronic structure</topic><topic>Enthalpy</topic><topic>Entropy</topic><topic>Essential oils</topic><topic>Free energy</topic><topic>Herbal medicine</topic><topic>Low carbon steels</topic><topic>Materials Science</topic><topic>Medicinal plants</topic><topic>Oils & fats</topic><topic>Parameters</topic><topic>Quantum chemistry</topic><topic>Solid Mechanics</topic><topic>Spectroscopy</topic><topic>Steel</topic><topic>Sulfuric acid</topic><topic>Tribology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mirinioui, Amine</creatorcontrib><creatorcontrib>El Attari, Hassan</creatorcontrib><creatorcontrib>Fdil, Rabiaa</creatorcontrib><creatorcontrib>Zefzoufi, Manal</creatorcontrib><creatorcontrib>Jorio, Souad</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of bio- and tribo-corrosion</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mirinioui, Amine</au><au>El Attari, Hassan</au><au>Fdil, Rabiaa</au><au>Zefzoufi, Manal</au><au>Jorio, Souad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dysphania ambrosioides Essential Oil: An Eco-friendly Inhibitor for Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Medium</atitle><jtitle>Journal of bio- and tribo-corrosion</jtitle><stitle>J Bio Tribo Corros</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>7</volume><issue>4</issue><artnum>150</artnum><issn>2198-4220</issn><eissn>2198-4239</eissn><abstract>The medicinal plant products have been found to be active and eco-friendly anticorrosion agents. Corrosion inhibition of essential oil of
Dysphania ambrosioides
(
DAEO
) were investigated on mild steel C38 in 0.5 M H
2
SO
4
and 1 M HCl solutions at different concentrations effect and different temperatures was evaluated using the weight-loss method and electrochemical measurements. The results indicated a maximum inhibition efficiency of 90% in 1 M HCl and 91% in 0.5 M H
2
SO
4
which was reached using 4 g/L of
DAEO
at 298 K. The results obtained by electrochemical impedance spectroscopy show that the inhibitory action of this extract is based on the increase of the charge transfer resistance and the decrease of the double layer capacity. In addition, thermodynamic parameters, such as standard enthalpy of adsorption (Δ
H°
ads
), standard free energy adsorption rate (Δ
G°
ads
), and standard entropy of adsorption (Δ
S°
ads
) were used to elucidate
DAEO
inhibitory action. In particular, density-functional theory (DFT) based methods, very suitable to study the electronic structure of mild steel and the main
DAEO
products. The quantum chemical parameters were measured and discussed.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s40735-021-00584-7</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2198-4220 |
| ispartof | Journal of bio- and tribo-corrosion, 2021-12, Vol.7 (4), Article 150 |
| issn | 2198-4220 2198-4239 |
| language | eng |
| recordid | cdi_proquest_journals_2575849180 |
| source | Springer Nature |
| subjects | Adsorption Biomaterials Charge transfer Chemistry and Materials Science Corrosion Corrosion and Coatings Corrosion inhibitors Corrosion prevention Corrosion products Density functional theory Dysphania ambrosioides Electrochemical impedance spectroscopy Electronic structure Enthalpy Entropy Essential oils Free energy Herbal medicine Low carbon steels Materials Science Medicinal plants Oils & fats Parameters Quantum chemistry Solid Mechanics Spectroscopy Steel Sulfuric acid Tribology |
| title | Dysphania ambrosioides Essential Oil: An Eco-friendly Inhibitor for Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Medium |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-24T13%3A03%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dysphania%20ambrosioides%20Essential%20Oil:%20An%20Eco-friendly%20Inhibitor%20for%20Mild%20Steel%20Corrosion%20in%20Hydrochloric%20and%20Sulfuric%20Acid%20Medium&rft.jtitle=Journal%20of%20bio-%20and%20tribo-corrosion&rft.au=Mirinioui,%20Amine&rft.date=2021-12-01&rft.volume=7&rft.issue=4&rft.artnum=150&rft.issn=2198-4220&rft.eissn=2198-4239&rft_id=info:doi/10.1007/s40735-021-00584-7&rft_dat=%3Cproquest_cross%3E2575849180%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c2347-61fdbd418a125e5511adadca57ca3971dd7da57863a571b810e64d585a97704f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2575849180&rft_id=info:pmid/&rfr_iscdi=true |