Sb–doped ZnO ceramics: NTC thermistors with high temperature sensitivity and electrical stability

• Published in: Journal of materials science. Materials in electronics 2021-10, Vol.32 (19), p.24296-24307
• Main Authors: Li, Bicai, Li, Zhicheng, Peng, Dicheng, Huang, Linling, Zhang, Shuyan, Zhang, Hong
• Format: Article
• Language: English
• Subjects: Aging; Aging (artificial); Ceramics; Characterization and Evaluation of Materials; Chemistry and Materials Science; Electrical properties; Electrical resistivity; High temperature; Materials Science; Optical and Electronic Materials; Room temperature; Sensitivity; Temperature; Thermistors; Wurtzite; Zinc oxide
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-021-06896-1

Sb-modified ZnO ceramics (Zn 1 −  x Sb x O, x  = 0, 0.001, 0.003, 0.005, 0.007, 0.010, 0.015, 0.020, 0.025) were prepared by the conventional solid-state reaction process. The phase component, electrical properties and electrical stabilities were investigated. Zn 1 −  x Sb x O ceramics have hexagonal wurtzite structure and show typical characteristics of negative temperature coefficient of resistivity. The room temperature resistivity and temperature sensitivity can be adjusted by Sb element doping. For various contents of Sb-ions, the prepared ceramics have temperature sensitivity of B 25/85 values from 2284 to 4754 K. After aging treatment at 150 °C, the ceramics have resistance change rates (Δ R / R 0 ) ranging from 1.44 to 2.17%. The aging induced change of resistance mainly resulted from the grain effect. The aging characteristics were discussed with the complex impedance spectra of ceramics and the variation of valent states of Sb-ions before and after aging.