Catalytic Hydrogenation of Furfural Diethyl Acetal to Ethyl Furfuryl Ether

The process of catalytic hydrogenation of furfural diethyl acetal to ethyl furfuryl ether on the different catalysts (palladium, palladium-rhenium and copper-ruthenium on Sibunit in reduced forms) was studied. It was found that hydrogenation of the furan ring with the formation of THF diethyl acetal...

Full description

Saved in:
Bibliographic Details
Published in:Journal of Siberian Federal University. Chemistry 2021-01, Vol.14 (3), p.281-289
Main Authors: Tarabanko, Valery E., Simakova, Irina L., Smirnova, Marina A., Kaygorodov, Konstantin L.
Format: Article
Language:English
Subjects:
Alcohol
Biodiesel fuels
Biofuels
Catalysts
Copper
Ethanol
Furfural
Hydrogen
Hydrogenation
Palladium
Rhenium
Ruthenium
Selectivity
Zeolites
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The process of catalytic hydrogenation of furfural diethyl acetal to ethyl furfuryl ether on the different catalysts (palladium, palladium-rhenium and copper-ruthenium on Sibunit in reduced forms) was studied. It was found that hydrogenation of the furan ring with the formation of THF diethyl acetal occurs on all the catalysts. Ethyl furfuryl ether becomes the main product while carrying on the second hydrogenation cycle on spent palladium catalyst (yield and selectivity up to 55 % and 85 %, respectively)
ISSN:1998-2836
2313-6049
DOI:10.17516/1998-2836-0237