Synthesis of Molybdenum Chelate-Bonded Fe3O4 Nanoparticles and Their Efficient Catalytic Activity in Epoxidation of Alkenes

Immobilization of Mo(VI) ions on magnetic nanoparticles has been performed using surface modification of Fe 3 O 4 with 2-hydroxy-5-(2-nitrophenyldiazenyl)benzaldehyde (HNPABA). The new nanomagnetic-supported organocatalyst (Fe 3 O 4 @SiO 2 −HNPABA−Mo(VI)) has been applied in epoxidation of olefins w...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of general chemistry 2021-09, Vol.91 (9), p.1789-1793
Main Authors: Menati, S., Mohseni, E., Gorjizadeh, M., Sayyahi, S.
Format: Article
Language:English
Subjects:
Alkenes
Benzaldehyde
Butyl hydroperoxide
Catalysts
Catalytic activity
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Epoxidation
Iron oxides
Molybdenum
Nanoparticles
Oxidizing agents
Silicon dioxide
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Immobilization of Mo(VI) ions on magnetic nanoparticles has been performed using surface modification of Fe 3 O 4 with 2-hydroxy-5-(2-nitrophenyldiazenyl)benzaldehyde (HNPABA). The new nanomagnetic-supported organocatalyst (Fe 3 O 4 @SiO 2 −HNPABA−Mo(VI)) has been applied in epoxidation of olefins with tert -butyl hydroperoxide. The results indicate that Fe 3 O 4 @SiO 2 −HNPABA−Mo(VI) magnetic nanoparticles demonstrate excellent activity and high stability. The effect of several parameters such as a solvent, catalyst, oxidant content, and temperature has been studied. In addition, the catalyst could be repeatedly applied up to five times without loss of activity in epoxidation of alkenes.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363221090267