Electrochemical fluorosulfonylation of styrenes

An environmentally friendly and efficient electrochemical fluorosulfonylation of styrenes has been developed. With the use of sulfonylhydrazides and triethylamine trihydrofluoride, a diverse array of β-fluorosulfones could be readily obtained. This reaction features mild conditions and a broad subst...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2021-11, Vol.57 (87), p.11481-11484
Main Authors: Jiang, Yi-Min, Yu, Yi, Wu, Shao-Fen, Yan, Hong, Yuan, Yaofeng, Ye, Ke-Yin
Format: Article
Language:English
Subjects:
Styrenes
Substrates
Triethylamine
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Summary:An environmentally friendly and efficient electrochemical fluorosulfonylation of styrenes has been developed. With the use of sulfonylhydrazides and triethylamine trihydrofluoride, a diverse array of β-fluorosulfones could be readily obtained. This reaction features mild conditions and a broad substrate scope, which could also be conveniently extended to a gram-scale preparation. An electrochemical preparation of β-fluorosulfones via assembly of the readily available styrenes, sulfonylhydrazides, and triethylamine trihydrofluoride, has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc04813a